1-(1-Carboxy­methyl-1,4-anhydro-2,3-O-isopropyl­idene-α-d-erythrofuranos­yl)thymine

X-Ray crystallography unequivocally determined the stereochemistry of the thymine base in the title compound, C(14)H(18)N(2)O(7). The absolute stereochemistry was determined from the use of d-ribose as the starting material. There are two independent mol­ecules in the asymmetric unit (Z′ = 2) which...

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Detalles Bibliográficos
Autores principales: Lenagh-Snow, G. M. J., Jenkinson, S. F., Stewart, A. J., Fleet, G. W. J., Watkin, D. J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979716/
https://www.ncbi.nlm.nih.gov/pubmed/21579824
http://dx.doi.org/10.1107/S1600536810001704
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author Lenagh-Snow, G. M. J.
Jenkinson, S. F.
Stewart, A. J.
Fleet, G. W. J.
Watkin, D. J.
author_facet Lenagh-Snow, G. M. J.
Jenkinson, S. F.
Stewart, A. J.
Fleet, G. W. J.
Watkin, D. J.
author_sort Lenagh-Snow, G. M. J.
collection PubMed
description X-Ray crystallography unequivocally determined the stereochemistry of the thymine base in the title compound, C(14)H(18)N(2)O(7). The absolute stereochemistry was determined from the use of d-ribose as the starting material. There are two independent mol­ecules in the asymmetric unit (Z′ = 2) which exist as N—H⋯O hydrogen-bonded pairs in the crystal structure.
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spelling pubmed-29797162010-12-30 1-(1-Carboxy­methyl-1,4-anhydro-2,3-O-isopropyl­idene-α-d-erythrofuranos­yl)thymine Lenagh-Snow, G. M. J. Jenkinson, S. F. Stewart, A. J. Fleet, G. W. J. Watkin, D. J. Acta Crystallogr Sect E Struct Rep Online Organic Papers X-Ray crystallography unequivocally determined the stereochemistry of the thymine base in the title compound, C(14)H(18)N(2)O(7). The absolute stereochemistry was determined from the use of d-ribose as the starting material. There are two independent mol­ecules in the asymmetric unit (Z′ = 2) which exist as N—H⋯O hydrogen-bonded pairs in the crystal structure. International Union of Crystallography 2010-01-20 /pmc/articles/PMC2979716/ /pubmed/21579824 http://dx.doi.org/10.1107/S1600536810001704 Text en © Lenagh-Snow et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lenagh-Snow, G. M. J.
Jenkinson, S. F.
Stewart, A. J.
Fleet, G. W. J.
Watkin, D. J.
1-(1-Carboxy­methyl-1,4-anhydro-2,3-O-isopropyl­idene-α-d-erythrofuranos­yl)thymine
title 1-(1-Carboxy­methyl-1,4-anhydro-2,3-O-isopropyl­idene-α-d-erythrofuranos­yl)thymine
title_full 1-(1-Carboxy­methyl-1,4-anhydro-2,3-O-isopropyl­idene-α-d-erythrofuranos­yl)thymine
title_fullStr 1-(1-Carboxy­methyl-1,4-anhydro-2,3-O-isopropyl­idene-α-d-erythrofuranos­yl)thymine
title_full_unstemmed 1-(1-Carboxy­methyl-1,4-anhydro-2,3-O-isopropyl­idene-α-d-erythrofuranos­yl)thymine
title_short 1-(1-Carboxy­methyl-1,4-anhydro-2,3-O-isopropyl­idene-α-d-erythrofuranos­yl)thymine
title_sort 1-(1-carboxy­methyl-1,4-anhydro-2,3-o-isopropyl­idene-α-d-erythrofuranos­yl)thymine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979716/
https://www.ncbi.nlm.nih.gov/pubmed/21579824
http://dx.doi.org/10.1107/S1600536810001704
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AT fleetgwj 11carboxymethyl14anhydro23oisopropylideneaderythrofuranosylthymine
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