6-Amino-9H-purine-1,7-diium bis­(4-methyl­benzene­sulfonate) monohydrate

The asymmetric unit of the title compound, C(5)H(7)N(5) (2+)·2C(7)H(7)O(3)S(−)·H(2)O, consists of one diprotonated adeninium cation, two p-toluene­sulfonic acid anions and one water mol­ecule. In the crystal, the cations and anions are connected through N—H⋯O hydrogen bonds forming R (2) (2)(8) and...

Descripción completa

Detalles Bibliográficos
Autores principales: Xiong, Zhi-Qiang, Ai, Yun-Long, Wen, Hui-Liang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979717/
https://www.ncbi.nlm.nih.gov/pubmed/21579748
http://dx.doi.org/10.1107/S1600536810000413
_version_ 1782191481962889216
author Xiong, Zhi-Qiang
Ai, Yun-Long
Wen, Hui-Liang
author_facet Xiong, Zhi-Qiang
Ai, Yun-Long
Wen, Hui-Liang
author_sort Xiong, Zhi-Qiang
collection PubMed
description The asymmetric unit of the title compound, C(5)H(7)N(5) (2+)·2C(7)H(7)O(3)S(−)·H(2)O, consists of one diprotonated adeninium cation, two p-toluene­sulfonic acid anions and one water mol­ecule. In the crystal, the cations and anions are connected through N—H⋯O hydrogen bonds forming R (2) (2)(8) and R (2) (2)(9) graph-set motifs. The solvent water mol­ecule links cations and anions through O—H⋯O and N—H⋯O hydrogen bonds, generating a two-dimensional layer parallel to (10[Image: see text]).
format Text
id pubmed-2979717
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29797172010-12-30 6-Amino-9H-purine-1,7-diium bis­(4-methyl­benzene­sulfonate) monohydrate Xiong, Zhi-Qiang Ai, Yun-Long Wen, Hui-Liang Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(5)H(7)N(5) (2+)·2C(7)H(7)O(3)S(−)·H(2)O, consists of one diprotonated adeninium cation, two p-toluene­sulfonic acid anions and one water mol­ecule. In the crystal, the cations and anions are connected through N—H⋯O hydrogen bonds forming R (2) (2)(8) and R (2) (2)(9) graph-set motifs. The solvent water mol­ecule links cations and anions through O—H⋯O and N—H⋯O hydrogen bonds, generating a two-dimensional layer parallel to (10[Image: see text]). International Union of Crystallography 2010-01-09 /pmc/articles/PMC2979717/ /pubmed/21579748 http://dx.doi.org/10.1107/S1600536810000413 Text en © Xiong et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Xiong, Zhi-Qiang
Ai, Yun-Long
Wen, Hui-Liang
6-Amino-9H-purine-1,7-diium bis­(4-methyl­benzene­sulfonate) monohydrate
title 6-Amino-9H-purine-1,7-diium bis­(4-methyl­benzene­sulfonate) monohydrate
title_full 6-Amino-9H-purine-1,7-diium bis­(4-methyl­benzene­sulfonate) monohydrate
title_fullStr 6-Amino-9H-purine-1,7-diium bis­(4-methyl­benzene­sulfonate) monohydrate
title_full_unstemmed 6-Amino-9H-purine-1,7-diium bis­(4-methyl­benzene­sulfonate) monohydrate
title_short 6-Amino-9H-purine-1,7-diium bis­(4-methyl­benzene­sulfonate) monohydrate
title_sort 6-amino-9h-purine-1,7-diium bis­(4-methyl­benzene­sulfonate) monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979717/
https://www.ncbi.nlm.nih.gov/pubmed/21579748
http://dx.doi.org/10.1107/S1600536810000413
work_keys_str_mv AT xiongzhiqiang 6amino9hpurine17diiumbis4methylbenzenesulfonatemonohydrate
AT aiyunlong 6amino9hpurine17diiumbis4methylbenzenesulfonatemonohydrate
AT wenhuiliang 6amino9hpurine17diiumbis4methylbenzenesulfonatemonohydrate

Ejemplares similares