[N,N′-Bis(4-chloro­phen­yl)pentane-2,4-diiminato]dicarbonyl­rhodium(I)

The title compound, [Rh(C(17)H(15)Cl(2)N(2))(CO)(2)], is a rhodium(I) derivative of a β-diketiminato moiety. It is an example of a new type of β-diketiminate derivative that has not yet been characterized via solid-state methods. The complex crystallizes with a distorted square-planar geometry about...

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Detalles Bibliográficos
Autores principales: Hill, T. N., Steyl, G.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979718/
https://www.ncbi.nlm.nih.gov/pubmed/21579669
http://dx.doi.org/10.1107/S1600536810000449
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author Hill, T. N.
Steyl, G.
author_facet Hill, T. N.
Steyl, G.
author_sort Hill, T. N.
collection PubMed
description The title compound, [Rh(C(17)H(15)Cl(2)N(2))(CO)(2)], is a rhodium(I) derivative of a β-diketiminato moiety. It is an example of a new type of β-diketiminate derivative that has not yet been characterized via solid-state methods. The complex crystallizes with a distorted square-planar geometry about the Rh(I) atom (m symmetry). A weak inter­molecular C—H⋯O contact is observed.
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spelling pubmed-29797182010-12-30 [N,N′-Bis(4-chloro­phen­yl)pentane-2,4-diiminato]dicarbonyl­rhodium(I) Hill, T. N. Steyl, G. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Rh(C(17)H(15)Cl(2)N(2))(CO)(2)], is a rhodium(I) derivative of a β-diketiminato moiety. It is an example of a new type of β-diketiminate derivative that has not yet been characterized via solid-state methods. The complex crystallizes with a distorted square-planar geometry about the Rh(I) atom (m symmetry). A weak inter­molecular C—H⋯O contact is observed. International Union of Crystallography 2010-01-27 /pmc/articles/PMC2979718/ /pubmed/21579669 http://dx.doi.org/10.1107/S1600536810000449 Text en © Hill and Steyl 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hill, T. N.
Steyl, G.
[N,N′-Bis(4-chloro­phen­yl)pentane-2,4-diiminato]dicarbonyl­rhodium(I)
title [N,N′-Bis(4-chloro­phen­yl)pentane-2,4-diiminato]dicarbonyl­rhodium(I)
title_full [N,N′-Bis(4-chloro­phen­yl)pentane-2,4-diiminato]dicarbonyl­rhodium(I)
title_fullStr [N,N′-Bis(4-chloro­phen­yl)pentane-2,4-diiminato]dicarbonyl­rhodium(I)
title_full_unstemmed [N,N′-Bis(4-chloro­phen­yl)pentane-2,4-diiminato]dicarbonyl­rhodium(I)
title_short [N,N′-Bis(4-chloro­phen­yl)pentane-2,4-diiminato]dicarbonyl­rhodium(I)
title_sort [n,n′-bis(4-chloro­phen­yl)pentane-2,4-diiminato]dicarbonyl­rhodium(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979718/
https://www.ncbi.nlm.nih.gov/pubmed/21579669
http://dx.doi.org/10.1107/S1600536810000449
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