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tert-Butoxytriphenylsilane
The title compound, C(22)H(24)OSi or Ph(3)SiO(t)Bu, shows a distorted tetrahedral coordination sphere around the Si atom. The C—O—Si angle is 135.97 (12)° and the O—Si distance is 1.6244 (13) Å. The molecules are held together by weak interactions only. An H⋯H distance of 2.2924 (7) Å is found be...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979722/ https://www.ncbi.nlm.nih.gov/pubmed/21579874 http://dx.doi.org/10.1107/S1600536810002722 |
| Sumario: | The title compound, C(22)H(24)OSi or Ph(3)SiO(t)Bu, shows a distorted tetrahedral coordination sphere around the Si atom. The C—O—Si angle is 135.97 (12)° and the O—Si distance is 1.6244 (13) Å. The molecules are held together by weak interactions only. An H⋯H distance of 2.2924 (7) Å is found between aryl H atoms and is the shortest intermolecular distance in the structure. With regard to the broad applicability of R (3)SiO structural motifs in all fields of chemistry, the molecule demonstrates a common model system for silicon centers surrounded by sterically demanding substituents. |
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