tert-Butoxy­triphenyl­silane

The title compound, C(22)H(24)OSi or Ph(3)SiO(t)Bu, shows a distorted tetra­hedral coordination sphere around the Si atom. The C—O—Si angle is 135.97 (12)° and the O—Si distance is 1.6244 (13) Å. The mol­ecules are held together by weak inter­actions only. An H⋯H distance of 2.2924 (7) Å is found be...

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Detalles Bibliográficos
Autores principales: Bauer, Jonathan O., Strohmann, Carsten
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979722/
https://www.ncbi.nlm.nih.gov/pubmed/21579874
http://dx.doi.org/10.1107/S1600536810002722
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author Bauer, Jonathan O.
Strohmann, Carsten
author_facet Bauer, Jonathan O.
Strohmann, Carsten
author_sort Bauer, Jonathan O.
collection PubMed
description The title compound, C(22)H(24)OSi or Ph(3)SiO(t)Bu, shows a distorted tetra­hedral coordination sphere around the Si atom. The C—O—Si angle is 135.97 (12)° and the O—Si distance is 1.6244 (13) Å. The mol­ecules are held together by weak inter­actions only. An H⋯H distance of 2.2924 (7) Å is found between aryl H atoms and is the shortest inter­molecular distance in the structure. With regard to the broad applicability of R (3)SiO structural motifs in all fields of chemistry, the mol­ecule demonstrates a common model system for silicon centers surrounded by sterically demanding substituents.
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spelling pubmed-29797222010-12-30 tert-Butoxy­triphenyl­silane Bauer, Jonathan O. Strohmann, Carsten Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(22)H(24)OSi or Ph(3)SiO(t)Bu, shows a distorted tetra­hedral coordination sphere around the Si atom. The C—O—Si angle is 135.97 (12)° and the O—Si distance is 1.6244 (13) Å. The mol­ecules are held together by weak inter­actions only. An H⋯H distance of 2.2924 (7) Å is found between aryl H atoms and is the shortest inter­molecular distance in the structure. With regard to the broad applicability of R (3)SiO structural motifs in all fields of chemistry, the mol­ecule demonstrates a common model system for silicon centers surrounded by sterically demanding substituents. International Union of Crystallography 2010-01-27 /pmc/articles/PMC2979722/ /pubmed/21579874 http://dx.doi.org/10.1107/S1600536810002722 Text en © Bauer and Strohmann 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Bauer, Jonathan O.
Strohmann, Carsten
tert-Butoxy­triphenyl­silane
title tert-Butoxy­triphenyl­silane
title_full tert-Butoxy­triphenyl­silane
title_fullStr tert-Butoxy­triphenyl­silane
title_full_unstemmed tert-Butoxy­triphenyl­silane
title_short tert-Butoxy­triphenyl­silane
title_sort tert-butoxy­triphenyl­silane
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979722/
https://www.ncbi.nlm.nih.gov/pubmed/21579874
http://dx.doi.org/10.1107/S1600536810002722
work_keys_str_mv AT bauerjonathano tertbutoxytriphenylsilane
AT strohmanncarsten tertbutoxytriphenylsilane

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