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Triethylammonium bis(2-oxido-2,2-diphenylacetato-κ(2) O (1),O (2))antimonate(III)
The coordination around the Sb atom in the title compound, (C(6)H(16)N)[Sb(C(14)H(10)O(3))(2)], is fourfold in a pseudo-trigonal-bipyramidal pattern in which one of the equatorial sites is occupied by the stereoactive lone pair of electrons. The four ligating atoms comprise the hydoxylate and carbox...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979724/ https://www.ncbi.nlm.nih.gov/pubmed/21579604 http://dx.doi.org/10.1107/S1600536809054853 |
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author | Reza, Md. Yeamin Hossain, Md. Motahar Karim, Md. Rabiul Tarafder, Md. Tofazzal Hossain Hughes, David L. |
author_facet | Reza, Md. Yeamin Hossain, Md. Motahar Karim, Md. Rabiul Tarafder, Md. Tofazzal Hossain Hughes, David L. |
author_sort | Reza, Md. Yeamin |
collection | PubMed |
description | The coordination around the Sb atom in the title compound, (C(6)H(16)N)[Sb(C(14)H(10)O(3))(2)], is fourfold in a pseudo-trigonal-bipyramidal pattern in which one of the equatorial sites is occupied by the stereoactive lone pair of electrons. The four ligating atoms comprise the hydoxylate and carboxylate O atoms from two independent benzilate ligands, each of which forms a five-membered chelating ring, spanning an axial and an equatorial site about the Sb atom. The hydroxylate atoms occupy the two equatorial sites, and the carboxylate atoms are in the pseudo-axial sites; the O—Sb—O angle is 147.72 (5)°. One carboxylate group shows quite different bond lengths from those of the other group; one O atom is clearly the carbonyl atom and the other O atom the hydroxylate atom. In the other ligand, there is less distinction in the C—O bonds. This is presumably related to the carbonyl O atom being the acceptor atom of a strong N—H⋯O hydrogen bond, which links the ammonium cation to the Sb complex anion. |
format | Text |
id | pubmed-2979724 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29797242010-12-30 Triethylammonium bis(2-oxido-2,2-diphenylacetato-κ(2) O (1),O (2))antimonate(III) Reza, Md. Yeamin Hossain, Md. Motahar Karim, Md. Rabiul Tarafder, Md. Tofazzal Hossain Hughes, David L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The coordination around the Sb atom in the title compound, (C(6)H(16)N)[Sb(C(14)H(10)O(3))(2)], is fourfold in a pseudo-trigonal-bipyramidal pattern in which one of the equatorial sites is occupied by the stereoactive lone pair of electrons. The four ligating atoms comprise the hydoxylate and carboxylate O atoms from two independent benzilate ligands, each of which forms a five-membered chelating ring, spanning an axial and an equatorial site about the Sb atom. The hydroxylate atoms occupy the two equatorial sites, and the carboxylate atoms are in the pseudo-axial sites; the O—Sb—O angle is 147.72 (5)°. One carboxylate group shows quite different bond lengths from those of the other group; one O atom is clearly the carbonyl atom and the other O atom the hydroxylate atom. In the other ligand, there is less distinction in the C—O bonds. This is presumably related to the carbonyl O atom being the acceptor atom of a strong N—H⋯O hydrogen bond, which links the ammonium cation to the Sb complex anion. International Union of Crystallography 2010-01-09 /pmc/articles/PMC2979724/ /pubmed/21579604 http://dx.doi.org/10.1107/S1600536809054853 Text en © Reza et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Reza, Md. Yeamin Hossain, Md. Motahar Karim, Md. Rabiul Tarafder, Md. Tofazzal Hossain Hughes, David L. Triethylammonium bis(2-oxido-2,2-diphenylacetato-κ(2) O (1),O (2))antimonate(III) |
title | Triethylammonium bis(2-oxido-2,2-diphenylacetato-κ(2)
O
(1),O
(2))antimonate(III) |
title_full | Triethylammonium bis(2-oxido-2,2-diphenylacetato-κ(2)
O
(1),O
(2))antimonate(III) |
title_fullStr | Triethylammonium bis(2-oxido-2,2-diphenylacetato-κ(2)
O
(1),O
(2))antimonate(III) |
title_full_unstemmed | Triethylammonium bis(2-oxido-2,2-diphenylacetato-κ(2)
O
(1),O
(2))antimonate(III) |
title_short | Triethylammonium bis(2-oxido-2,2-diphenylacetato-κ(2)
O
(1),O
(2))antimonate(III) |
title_sort | triethylammonium bis(2-oxido-2,2-diphenylacetato-κ(2)
o
(1),o
(2))antimonate(iii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979724/ https://www.ncbi.nlm.nih.gov/pubmed/21579604 http://dx.doi.org/10.1107/S1600536809054853 |
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