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Triethyl­ammonium bis­(2-oxido-2,2-diphenyl­acetato-κ(2) O (1),O (2))anti­monate(III)

The coordination around the Sb atom in the title compound, (C(6)H(16)N)[Sb(C(14)H(10)O(3))(2)], is fourfold in a pseudo-trigonal-bipyramidal pattern in which one of the equatorial sites is occupied by the stereoactive lone pair of electrons. The four ligating atoms comprise the hydoxylate and carbox...

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Autores principales: Reza, Md. Yeamin, Hossain, Md. Motahar, Karim, Md. Rabiul, Tarafder, Md. Tofazzal Hossain, Hughes, David L.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979724/
https://www.ncbi.nlm.nih.gov/pubmed/21579604
http://dx.doi.org/10.1107/S1600536809054853
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author Reza, Md. Yeamin
Hossain, Md. Motahar
Karim, Md. Rabiul
Tarafder, Md. Tofazzal Hossain
Hughes, David L.
author_facet Reza, Md. Yeamin
Hossain, Md. Motahar
Karim, Md. Rabiul
Tarafder, Md. Tofazzal Hossain
Hughes, David L.
author_sort Reza, Md. Yeamin
collection PubMed
description The coordination around the Sb atom in the title compound, (C(6)H(16)N)[Sb(C(14)H(10)O(3))(2)], is fourfold in a pseudo-trigonal-bipyramidal pattern in which one of the equatorial sites is occupied by the stereoactive lone pair of electrons. The four ligating atoms comprise the hydoxylate and carboxyl­ate O atoms from two independent benzilate ligands, each of which forms a five-membered chelating ring, spanning an axial and an equatorial site about the Sb atom. The hydroxy­late atoms occupy the two equatorial sites, and the carboxyl­ate atoms are in the pseudo-axial sites; the O—Sb—O angle is 147.72 (5)°. One carboxyl­ate group shows quite different bond lengths from those of the other group; one O atom is clearly the carbonyl atom and the other O atom the hydroxy­late atom. In the other ligand, there is less distinction in the C—O bonds. This is presumably related to the carbonyl O atom being the acceptor atom of a strong N—H⋯O hydrogen bond, which links the ammonium cation to the Sb complex anion.
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spelling pubmed-29797242010-12-30 Triethyl­ammonium bis­(2-oxido-2,2-diphenyl­acetato-κ(2) O (1),O (2))anti­monate(III) Reza, Md. Yeamin Hossain, Md. Motahar Karim, Md. Rabiul Tarafder, Md. Tofazzal Hossain Hughes, David L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The coordination around the Sb atom in the title compound, (C(6)H(16)N)[Sb(C(14)H(10)O(3))(2)], is fourfold in a pseudo-trigonal-bipyramidal pattern in which one of the equatorial sites is occupied by the stereoactive lone pair of electrons. The four ligating atoms comprise the hydoxylate and carboxyl­ate O atoms from two independent benzilate ligands, each of which forms a five-membered chelating ring, spanning an axial and an equatorial site about the Sb atom. The hydroxy­late atoms occupy the two equatorial sites, and the carboxyl­ate atoms are in the pseudo-axial sites; the O—Sb—O angle is 147.72 (5)°. One carboxyl­ate group shows quite different bond lengths from those of the other group; one O atom is clearly the carbonyl atom and the other O atom the hydroxy­late atom. In the other ligand, there is less distinction in the C—O bonds. This is presumably related to the carbonyl O atom being the acceptor atom of a strong N—H⋯O hydrogen bond, which links the ammonium cation to the Sb complex anion. International Union of Crystallography 2010-01-09 /pmc/articles/PMC2979724/ /pubmed/21579604 http://dx.doi.org/10.1107/S1600536809054853 Text en © Reza et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Reza, Md. Yeamin
Hossain, Md. Motahar
Karim, Md. Rabiul
Tarafder, Md. Tofazzal Hossain
Hughes, David L.
Triethyl­ammonium bis­(2-oxido-2,2-diphenyl­acetato-κ(2) O (1),O (2))anti­monate(III)
title Triethyl­ammonium bis­(2-oxido-2,2-diphenyl­acetato-κ(2) O (1),O (2))anti­monate(III)
title_full Triethyl­ammonium bis­(2-oxido-2,2-diphenyl­acetato-κ(2) O (1),O (2))anti­monate(III)
title_fullStr Triethyl­ammonium bis­(2-oxido-2,2-diphenyl­acetato-κ(2) O (1),O (2))anti­monate(III)
title_full_unstemmed Triethyl­ammonium bis­(2-oxido-2,2-diphenyl­acetato-κ(2) O (1),O (2))anti­monate(III)
title_short Triethyl­ammonium bis­(2-oxido-2,2-diphenyl­acetato-κ(2) O (1),O (2))anti­monate(III)
title_sort triethyl­ammonium bis­(2-oxido-2,2-diphenyl­acetato-κ(2) o (1),o (2))anti­monate(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979724/
https://www.ncbi.nlm.nih.gov/pubmed/21579604
http://dx.doi.org/10.1107/S1600536809054853
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