Ethyl 2-{[(1Z)-(3-methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-yl­idene)(p-tol­yl)meth­yl]amino}-3-phenyl­propanoate

The asymmetric unit of the title compound, C(29)H(29)N(3)O(3), contains two mol­ecules, which exist in their enamine–keto form, being stabilized by strong intra­molecular N—H⋯O hydrogen bonds, which generate S(6) loops. In the crystal, inter­molecular C–H⋯O hydrogen bonds link the mol­ecules into ch...

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Detalles Bibliográficos
Autores principales: Zhang, Xin, Huang, Meng, Du, Cong, Han, Junjing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979726/
https://www.ncbi.nlm.nih.gov/pubmed/21579710
http://dx.doi.org/10.1107/S1600536809054865
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author Zhang, Xin
Huang, Meng
Du, Cong
Han, Junjing
author_facet Zhang, Xin
Huang, Meng
Du, Cong
Han, Junjing
author_sort Zhang, Xin
collection PubMed
description The asymmetric unit of the title compound, C(29)H(29)N(3)O(3), contains two mol­ecules, which exist in their enamine–keto form, being stabilized by strong intra­molecular N—H⋯O hydrogen bonds, which generate S(6) loops. In the crystal, inter­molecular C–H⋯O hydrogen bonds link the mol­ecules into chains, which are further linked by weak C—H⋯π inter­actions, forming a two-dimensional network.
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spelling pubmed-29797262010-12-30 Ethyl 2-{[(1Z)-(3-methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-yl­idene)(p-tol­yl)meth­yl]amino}-3-phenyl­propanoate Zhang, Xin Huang, Meng Du, Cong Han, Junjing Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(29)H(29)N(3)O(3), contains two mol­ecules, which exist in their enamine–keto form, being stabilized by strong intra­molecular N—H⋯O hydrogen bonds, which generate S(6) loops. In the crystal, inter­molecular C–H⋯O hydrogen bonds link the mol­ecules into chains, which are further linked by weak C—H⋯π inter­actions, forming a two-dimensional network. International Union of Crystallography 2010-01-09 /pmc/articles/PMC2979726/ /pubmed/21579710 http://dx.doi.org/10.1107/S1600536809054865 Text en © Zhang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhang, Xin
Huang, Meng
Du, Cong
Han, Junjing
Ethyl 2-{[(1Z)-(3-methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-yl­idene)(p-tol­yl)meth­yl]amino}-3-phenyl­propanoate
title Ethyl 2-{[(1Z)-(3-methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-yl­idene)(p-tol­yl)meth­yl]amino}-3-phenyl­propanoate
title_full Ethyl 2-{[(1Z)-(3-methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-yl­idene)(p-tol­yl)meth­yl]amino}-3-phenyl­propanoate
title_fullStr Ethyl 2-{[(1Z)-(3-methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-yl­idene)(p-tol­yl)meth­yl]amino}-3-phenyl­propanoate
title_full_unstemmed Ethyl 2-{[(1Z)-(3-methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-yl­idene)(p-tol­yl)meth­yl]amino}-3-phenyl­propanoate
title_short Ethyl 2-{[(1Z)-(3-methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-yl­idene)(p-tol­yl)meth­yl]amino}-3-phenyl­propanoate
title_sort ethyl 2-{[(1z)-(3-methyl-5-oxo-1-phenyl-4,5-dihydro-1h-pyrazol-4-yl­idene)(p-tol­yl)meth­yl]amino}-3-phenyl­propanoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979726/
https://www.ncbi.nlm.nih.gov/pubmed/21579710
http://dx.doi.org/10.1107/S1600536809054865
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AT ducong ethyl21z3methyl5oxo1phenyl45dihydro1hpyrazol4ylideneptolylmethylamino3phenylpropanoate
AT hanjunjing ethyl21z3methyl5oxo1phenyl45dihydro1hpyrazol4ylideneptolylmethylamino3phenylpropanoate

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