1-(2-Cyano­ethyl)-2-(2-pyrid­yl)-1H,3H-benzimidazol-3-ium perchlorate

The title compound, C(15)H(13)N(4) (+)·ClO(4) (−), comprises a nonplanar 1-(2-cyano­ethyl)-2-(2-pyrid­yl)-1H,3H-benzimidazol-3-ium cation [dihedral angle between the imidazole and pyridine rings = 22.5 (8)°] and a perchlorate anion. The cation is formed by protonation of the N atom of the benzimidaz...

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Detalles Bibliográficos
Autores principales: Li, Yan, Tang, Xiaoliang, Chen, Jiayu, Wu, Daxiang, Liu, Weisheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979728/
https://www.ncbi.nlm.nih.gov/pubmed/21579831
http://dx.doi.org/10.1107/S1600536809055251
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author Li, Yan
Tang, Xiaoliang
Chen, Jiayu
Wu, Daxiang
Liu, Weisheng
author_facet Li, Yan
Tang, Xiaoliang
Chen, Jiayu
Wu, Daxiang
Liu, Weisheng
author_sort Li, Yan
collection PubMed
description The title compound, C(15)H(13)N(4) (+)·ClO(4) (−), comprises a nonplanar 1-(2-cyano­ethyl)-2-(2-pyrid­yl)-1H,3H-benzimidazol-3-ium cation [dihedral angle between the imidazole and pyridine rings = 22.5 (8)°] and a perchlorate anion. The cation is formed by protonation of the N atom of the benzimidazole ring. A charged N—H⋯O hydrogen bond connects the anion and cation, and inter­molecular C—H⋯O and C—H⋯N inter­actions contribute to the crystal packing.
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spelling pubmed-29797282010-12-30 1-(2-Cyano­ethyl)-2-(2-pyrid­yl)-1H,3H-benzimidazol-3-ium perchlorate Li, Yan Tang, Xiaoliang Chen, Jiayu Wu, Daxiang Liu, Weisheng Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(13)N(4) (+)·ClO(4) (−), comprises a nonplanar 1-(2-cyano­ethyl)-2-(2-pyrid­yl)-1H,3H-benzimidazol-3-ium cation [dihedral angle between the imidazole and pyridine rings = 22.5 (8)°] and a perchlorate anion. The cation is formed by protonation of the N atom of the benzimidazole ring. A charged N—H⋯O hydrogen bond connects the anion and cation, and inter­molecular C—H⋯O and C—H⋯N inter­actions contribute to the crystal packing. International Union of Crystallography 2010-01-20 /pmc/articles/PMC2979728/ /pubmed/21579831 http://dx.doi.org/10.1107/S1600536809055251 Text en © Li et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Yan
Tang, Xiaoliang
Chen, Jiayu
Wu, Daxiang
Liu, Weisheng
1-(2-Cyano­ethyl)-2-(2-pyrid­yl)-1H,3H-benzimidazol-3-ium perchlorate
title 1-(2-Cyano­ethyl)-2-(2-pyrid­yl)-1H,3H-benzimidazol-3-ium perchlorate
title_full 1-(2-Cyano­ethyl)-2-(2-pyrid­yl)-1H,3H-benzimidazol-3-ium perchlorate
title_fullStr 1-(2-Cyano­ethyl)-2-(2-pyrid­yl)-1H,3H-benzimidazol-3-ium perchlorate
title_full_unstemmed 1-(2-Cyano­ethyl)-2-(2-pyrid­yl)-1H,3H-benzimidazol-3-ium perchlorate
title_short 1-(2-Cyano­ethyl)-2-(2-pyrid­yl)-1H,3H-benzimidazol-3-ium perchlorate
title_sort 1-(2-cyano­ethyl)-2-(2-pyrid­yl)-1h,3h-benzimidazol-3-ium perchlorate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979728/
https://www.ncbi.nlm.nih.gov/pubmed/21579831
http://dx.doi.org/10.1107/S1600536809055251
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AT tangxiaoliang 12cyanoethyl22pyridyl1h3hbenzimidazol3iumperchlorate
AT chenjiayu 12cyanoethyl22pyridyl1h3hbenzimidazol3iumperchlorate
AT wudaxiang 12cyanoethyl22pyridyl1h3hbenzimidazol3iumperchlorate
AT liuweisheng 12cyanoethyl22pyridyl1h3hbenzimidazol3iumperchlorate

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