catena-Poly[diquinolinium [[diaqua­cobaltate(II)]-μ-cyclo­tetra­phosphato] hexa­hydrate]

The cyclo­tetra­phosphate anion, [P(4)O(12)](4−), forms the title complex with cobalt(II) and quinolinium, {(C(9)H(8)N)(2)[Co(P(4)O(12))(H(2)O)(2)]·6H(2)O}(n). In the complex anion, the Co(II) ion, lying on an inversion center, is surrounded by four phosphate O atoms and two water mol­ecules in a sl...

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Detalles Bibliográficos
Autores principales: Hemissi, Hanène, Rzaigui, Mohammed, Al Othman, Zeid Abdullah
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979730/
https://www.ncbi.nlm.nih.gov/pubmed/21579654
http://dx.doi.org/10.1107/S1600536810002096
Descripción
Sumario:The cyclo­tetra­phosphate anion, [P(4)O(12)](4−), forms the title complex with cobalt(II) and quinolinium, {(C(9)H(8)N)(2)[Co(P(4)O(12))(H(2)O)(2)]·6H(2)O}(n). In the complex anion, the Co(II) ion, lying on an inversion center, is surrounded by four phosphate O atoms and two water mol­ecules in a slightly distorted octa­hedral geometry. The crystal structure consists of anionic ribbons of formula {[Co(P(4)O(12))(H(2)O)(2)](2−)}(n) extending along [100]. A network of O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds consolidates the crystal packing.

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