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Poly[[aqua(μ(4)-1H-benzimidazole-5,6-dicarboxylato-κ(4) N (3):O (5):O (5′):O (6))(N,N-dimethylformamide-κO)cadmium(II)] dihydrate]
In the title compound, {[Cd(C(9)H(4)N(2)O(4))(C(3)H(7)NO)(H(2)O)]·2H(2)O}(n), the Cd(II) atom is coordinated by one N atom and three O atoms from four different 1H-benzimidazole-5,6-dicarboxylate (Hbidc) ligands, one O atom from one dimethylformamide ligand, and one O atom from a water molecule i...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979735/ https://www.ncbi.nlm.nih.gov/pubmed/21579672 http://dx.doi.org/10.1107/S1600536810003065 |
Sumario: | In the title compound, {[Cd(C(9)H(4)N(2)O(4))(C(3)H(7)NO)(H(2)O)]·2H(2)O}(n), the Cd(II) atom is coordinated by one N atom and three O atoms from four different 1H-benzimidazole-5,6-dicarboxylate (Hbidc) ligands, one O atom from one dimethylformamide ligand, and one O atom from a water molecule in a distorted octahedral geometry. The Hbidc ligands connect the Cd atoms into a two-dimensional network parallel to (001). N—H⋯O and O—H⋯O hydrogen bonds involving the water molecules are observed in the crystal structure. |
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