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Poly[[aqua(μ(4)-1H-benzimidazole-5,6-dicarboxylato-κ(4) N (3):O (5):O (5′):O (6))(N,N-dimethylformamide-κO)cadmium(II)] dihydrate]
In the title compound, {[Cd(C(9)H(4)N(2)O(4))(C(3)H(7)NO)(H(2)O)]·2H(2)O}(n), the Cd(II) atom is coordinated by one N atom and three O atoms from four different 1H-benzimidazole-5,6-dicarboxylate (Hbidc) ligands, one O atom from one dimethylformamide ligand, and one O atom from a water molecule i...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979735/ https://www.ncbi.nlm.nih.gov/pubmed/21579672 http://dx.doi.org/10.1107/S1600536810003065 |
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author | Wang, Hao Li, Shi-Jie Song, Wen-Dong Li, Xiao-Fei Miao, Dong-Liang |
author_facet | Wang, Hao Li, Shi-Jie Song, Wen-Dong Li, Xiao-Fei Miao, Dong-Liang |
author_sort | Wang, Hao |
collection | PubMed |
description | In the title compound, {[Cd(C(9)H(4)N(2)O(4))(C(3)H(7)NO)(H(2)O)]·2H(2)O}(n), the Cd(II) atom is coordinated by one N atom and three O atoms from four different 1H-benzimidazole-5,6-dicarboxylate (Hbidc) ligands, one O atom from one dimethylformamide ligand, and one O atom from a water molecule in a distorted octahedral geometry. The Hbidc ligands connect the Cd atoms into a two-dimensional network parallel to (001). N—H⋯O and O—H⋯O hydrogen bonds involving the water molecules are observed in the crystal structure. |
format | Text |
id | pubmed-2979735 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29797352010-12-30 Poly[[aqua(μ(4)-1H-benzimidazole-5,6-dicarboxylato-κ(4) N (3):O (5):O (5′):O (6))(N,N-dimethylformamide-κO)cadmium(II)] dihydrate] Wang, Hao Li, Shi-Jie Song, Wen-Dong Li, Xiao-Fei Miao, Dong-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Cd(C(9)H(4)N(2)O(4))(C(3)H(7)NO)(H(2)O)]·2H(2)O}(n), the Cd(II) atom is coordinated by one N atom and three O atoms from four different 1H-benzimidazole-5,6-dicarboxylate (Hbidc) ligands, one O atom from one dimethylformamide ligand, and one O atom from a water molecule in a distorted octahedral geometry. The Hbidc ligands connect the Cd atoms into a two-dimensional network parallel to (001). N—H⋯O and O—H⋯O hydrogen bonds involving the water molecules are observed in the crystal structure. International Union of Crystallography 2010-01-30 /pmc/articles/PMC2979735/ /pubmed/21579672 http://dx.doi.org/10.1107/S1600536810003065 Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Hao Li, Shi-Jie Song, Wen-Dong Li, Xiao-Fei Miao, Dong-Liang Poly[[aqua(μ(4)-1H-benzimidazole-5,6-dicarboxylato-κ(4) N (3):O (5):O (5′):O (6))(N,N-dimethylformamide-κO)cadmium(II)] dihydrate] |
title | Poly[[aqua(μ(4)-1H-benzimidazole-5,6-dicarboxylato-κ(4)
N
(3):O
(5):O
(5′):O
(6))(N,N-dimethylformamide-κO)cadmium(II)] dihydrate] |
title_full | Poly[[aqua(μ(4)-1H-benzimidazole-5,6-dicarboxylato-κ(4)
N
(3):O
(5):O
(5′):O
(6))(N,N-dimethylformamide-κO)cadmium(II)] dihydrate] |
title_fullStr | Poly[[aqua(μ(4)-1H-benzimidazole-5,6-dicarboxylato-κ(4)
N
(3):O
(5):O
(5′):O
(6))(N,N-dimethylformamide-κO)cadmium(II)] dihydrate] |
title_full_unstemmed | Poly[[aqua(μ(4)-1H-benzimidazole-5,6-dicarboxylato-κ(4)
N
(3):O
(5):O
(5′):O
(6))(N,N-dimethylformamide-κO)cadmium(II)] dihydrate] |
title_short | Poly[[aqua(μ(4)-1H-benzimidazole-5,6-dicarboxylato-κ(4)
N
(3):O
(5):O
(5′):O
(6))(N,N-dimethylformamide-κO)cadmium(II)] dihydrate] |
title_sort | poly[[aqua(μ(4)-1h-benzimidazole-5,6-dicarboxylato-κ(4)
n
(3):o
(5):o
(5′):o
(6))(n,n-dimethylformamide-κo)cadmium(ii)] dihydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979735/ https://www.ncbi.nlm.nih.gov/pubmed/21579672 http://dx.doi.org/10.1107/S1600536810003065 |
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