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Poly[[aqua­(μ(4)-1H-benzimidazole-5,6-dicarboxyl­ato-κ(4) N (3):O (5):O (5′):O (6))(N,N-dimethyl­formamide-κO)cadmium(II)] dihydrate]

In the title compound, {[Cd(C(9)H(4)N(2)O(4))(C(3)H(7)NO)(H(2)O)]·2H(2)O}(n), the Cd(II) atom is coordinated by one N atom and three O atoms from four different 1H-benzimidazole-5,6-dicarboxyl­ate (Hbidc) ligands, one O atom from one dimethyl­formamide ligand, and one O atom from a water mol­ecule i...

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Detalles Bibliográficos
Autores principales: Wang, Hao, Li, Shi-Jie, Song, Wen-Dong, Li, Xiao-Fei, Miao, Dong-Liang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979735/
https://www.ncbi.nlm.nih.gov/pubmed/21579672
http://dx.doi.org/10.1107/S1600536810003065
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author Wang, Hao
Li, Shi-Jie
Song, Wen-Dong
Li, Xiao-Fei
Miao, Dong-Liang
author_facet Wang, Hao
Li, Shi-Jie
Song, Wen-Dong
Li, Xiao-Fei
Miao, Dong-Liang
author_sort Wang, Hao
collection PubMed
description In the title compound, {[Cd(C(9)H(4)N(2)O(4))(C(3)H(7)NO)(H(2)O)]·2H(2)O}(n), the Cd(II) atom is coordinated by one N atom and three O atoms from four different 1H-benzimidazole-5,6-dicarboxyl­ate (Hbidc) ligands, one O atom from one dimethyl­formamide ligand, and one O atom from a water mol­ecule in a distorted octa­hedral geometry. The Hbidc ligands connect the Cd atoms into a two-dimensional network parallel to (001). N—H⋯O and O—H⋯O hydrogen bonds involving the water molecules are observed in the crystal structure.
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spelling pubmed-29797352010-12-30 Poly[[aqua­(μ(4)-1H-benzimidazole-5,6-dicarboxyl­ato-κ(4) N (3):O (5):O (5′):O (6))(N,N-dimethyl­formamide-κO)cadmium(II)] dihydrate] Wang, Hao Li, Shi-Jie Song, Wen-Dong Li, Xiao-Fei Miao, Dong-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Cd(C(9)H(4)N(2)O(4))(C(3)H(7)NO)(H(2)O)]·2H(2)O}(n), the Cd(II) atom is coordinated by one N atom and three O atoms from four different 1H-benzimidazole-5,6-dicarboxyl­ate (Hbidc) ligands, one O atom from one dimethyl­formamide ligand, and one O atom from a water mol­ecule in a distorted octa­hedral geometry. The Hbidc ligands connect the Cd atoms into a two-dimensional network parallel to (001). N—H⋯O and O—H⋯O hydrogen bonds involving the water molecules are observed in the crystal structure. International Union of Crystallography 2010-01-30 /pmc/articles/PMC2979735/ /pubmed/21579672 http://dx.doi.org/10.1107/S1600536810003065 Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Hao
Li, Shi-Jie
Song, Wen-Dong
Li, Xiao-Fei
Miao, Dong-Liang
Poly[[aqua­(μ(4)-1H-benzimidazole-5,6-dicarboxyl­ato-κ(4) N (3):O (5):O (5′):O (6))(N,N-dimethyl­formamide-κO)cadmium(II)] dihydrate]
title Poly[[aqua­(μ(4)-1H-benzimidazole-5,6-dicarboxyl­ato-κ(4) N (3):O (5):O (5′):O (6))(N,N-dimethyl­formamide-κO)cadmium(II)] dihydrate]
title_full Poly[[aqua­(μ(4)-1H-benzimidazole-5,6-dicarboxyl­ato-κ(4) N (3):O (5):O (5′):O (6))(N,N-dimethyl­formamide-κO)cadmium(II)] dihydrate]
title_fullStr Poly[[aqua­(μ(4)-1H-benzimidazole-5,6-dicarboxyl­ato-κ(4) N (3):O (5):O (5′):O (6))(N,N-dimethyl­formamide-κO)cadmium(II)] dihydrate]
title_full_unstemmed Poly[[aqua­(μ(4)-1H-benzimidazole-5,6-dicarboxyl­ato-κ(4) N (3):O (5):O (5′):O (6))(N,N-dimethyl­formamide-κO)cadmium(II)] dihydrate]
title_short Poly[[aqua­(μ(4)-1H-benzimidazole-5,6-dicarboxyl­ato-κ(4) N (3):O (5):O (5′):O (6))(N,N-dimethyl­formamide-κO)cadmium(II)] dihydrate]
title_sort poly[[aqua­(μ(4)-1h-benzimidazole-5,6-dicarboxyl­ato-κ(4) n (3):o (5):o (5′):o (6))(n,n-dimethyl­formamide-κo)cadmium(ii)] dihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979735/
https://www.ncbi.nlm.nih.gov/pubmed/21579672
http://dx.doi.org/10.1107/S1600536810003065
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