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Bis(2,2′-bipyridyl)(dichloroacetato)copper(II) dichloroacetate dihydrate
In the title compound, [Cu(C(2)HCl(2)O(2))(C(10)H(8)N(2))(2)](C(2)HCl(2)O(2))·2H(2)O, the Cu(II) ion is bonded to two N,N′-bidentate 2,2′-bipyridyl ligands and one O-monodentate 2,2-dichloroacetate anion in a distorted CuON(4) trigonal-bipyramidal geometry, with the O atom occupying an equatorial s...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979737/ https://www.ncbi.nlm.nih.gov/pubmed/21579622 http://dx.doi.org/10.1107/S1600536809055640 |
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author | Li, Yu-Feng Wang, Lin-Tong Jian, Fang-Fang |
author_facet | Li, Yu-Feng Wang, Lin-Tong Jian, Fang-Fang |
author_sort | Li, Yu-Feng |
collection | PubMed |
description | In the title compound, [Cu(C(2)HCl(2)O(2))(C(10)H(8)N(2))(2)](C(2)HCl(2)O(2))·2H(2)O, the Cu(II) ion is bonded to two N,N′-bidentate 2,2′-bipyridyl ligands and one O-monodentate 2,2-dichloroacetate anion in a distorted CuON(4) trigonal-bipyramidal geometry, with the O atom occupying an equatorial site. In the crystal, the components are linked by O—H⋯O and O—H⋯Cl hydrogen bonds. |
format | Text |
id | pubmed-2979737 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29797372010-12-30 Bis(2,2′-bipyridyl)(dichloroacetato)copper(II) dichloroacetate dihydrate Li, Yu-Feng Wang, Lin-Tong Jian, Fang-Fang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(2)HCl(2)O(2))(C(10)H(8)N(2))(2)](C(2)HCl(2)O(2))·2H(2)O, the Cu(II) ion is bonded to two N,N′-bidentate 2,2′-bipyridyl ligands and one O-monodentate 2,2-dichloroacetate anion in a distorted CuON(4) trigonal-bipyramidal geometry, with the O atom occupying an equatorial site. In the crystal, the components are linked by O—H⋯O and O—H⋯Cl hydrogen bonds. International Union of Crystallography 2010-01-13 /pmc/articles/PMC2979737/ /pubmed/21579622 http://dx.doi.org/10.1107/S1600536809055640 Text en © Li et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Li, Yu-Feng Wang, Lin-Tong Jian, Fang-Fang Bis(2,2′-bipyridyl)(dichloroacetato)copper(II) dichloroacetate dihydrate |
title | Bis(2,2′-bipyridyl)(dichloroacetato)copper(II) dichloroacetate dihydrate |
title_full | Bis(2,2′-bipyridyl)(dichloroacetato)copper(II) dichloroacetate dihydrate |
title_fullStr | Bis(2,2′-bipyridyl)(dichloroacetato)copper(II) dichloroacetate dihydrate |
title_full_unstemmed | Bis(2,2′-bipyridyl)(dichloroacetato)copper(II) dichloroacetate dihydrate |
title_short | Bis(2,2′-bipyridyl)(dichloroacetato)copper(II) dichloroacetate dihydrate |
title_sort | bis(2,2′-bipyridyl)(dichloroacetato)copper(ii) dichloroacetate dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979737/ https://www.ncbi.nlm.nih.gov/pubmed/21579622 http://dx.doi.org/10.1107/S1600536809055640 |
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