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Bis(2,2′-bipyrid­yl)(dichloro­acetato)copper(II) dichloro­acetate dihydrate

In the title compound, [Cu(C(2)HCl(2)O(2))(C(10)H(8)N(2))(2)](C(2)HCl(2)O(2))·2H(2)O, the Cu(II) ion is bonded to two N,N′-bidentate 2,2′-bipyridyl ligands and one O-monodentate 2,2-dichloro­acetate anion in a distorted CuON(4) trigonal-bipyramidal geometry, with the O atom occupying an equatorial s...

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Detalles Bibliográficos
Autores principales: Li, Yu-Feng, Wang, Lin-Tong, Jian, Fang-Fang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979737/
https://www.ncbi.nlm.nih.gov/pubmed/21579622
http://dx.doi.org/10.1107/S1600536809055640
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author Li, Yu-Feng
Wang, Lin-Tong
Jian, Fang-Fang
author_facet Li, Yu-Feng
Wang, Lin-Tong
Jian, Fang-Fang
author_sort Li, Yu-Feng
collection PubMed
description In the title compound, [Cu(C(2)HCl(2)O(2))(C(10)H(8)N(2))(2)](C(2)HCl(2)O(2))·2H(2)O, the Cu(II) ion is bonded to two N,N′-bidentate 2,2′-bipyridyl ligands and one O-monodentate 2,2-dichloro­acetate anion in a distorted CuON(4) trigonal-bipyramidal geometry, with the O atom occupying an equatorial site. In the crystal, the components are linked by O—H⋯O and O—H⋯Cl hydrogen bonds.
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spelling pubmed-29797372010-12-30 Bis(2,2′-bipyrid­yl)(dichloro­acetato)copper(II) dichloro­acetate dihydrate Li, Yu-Feng Wang, Lin-Tong Jian, Fang-Fang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(2)HCl(2)O(2))(C(10)H(8)N(2))(2)](C(2)HCl(2)O(2))·2H(2)O, the Cu(II) ion is bonded to two N,N′-bidentate 2,2′-bipyridyl ligands and one O-monodentate 2,2-dichloro­acetate anion in a distorted CuON(4) trigonal-bipyramidal geometry, with the O atom occupying an equatorial site. In the crystal, the components are linked by O—H⋯O and O—H⋯Cl hydrogen bonds. International Union of Crystallography 2010-01-13 /pmc/articles/PMC2979737/ /pubmed/21579622 http://dx.doi.org/10.1107/S1600536809055640 Text en © Li et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Yu-Feng
Wang, Lin-Tong
Jian, Fang-Fang
Bis(2,2′-bipyrid­yl)(dichloro­acetato)copper(II) dichloro­acetate dihydrate
title Bis(2,2′-bipyrid­yl)(dichloro­acetato)copper(II) dichloro­acetate dihydrate
title_full Bis(2,2′-bipyrid­yl)(dichloro­acetato)copper(II) dichloro­acetate dihydrate
title_fullStr Bis(2,2′-bipyrid­yl)(dichloro­acetato)copper(II) dichloro­acetate dihydrate
title_full_unstemmed Bis(2,2′-bipyrid­yl)(dichloro­acetato)copper(II) dichloro­acetate dihydrate
title_short Bis(2,2′-bipyrid­yl)(dichloro­acetato)copper(II) dichloro­acetate dihydrate
title_sort bis(2,2′-bipyrid­yl)(dichloro­acetato)copper(ii) dichloro­acetate dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979737/
https://www.ncbi.nlm.nih.gov/pubmed/21579622
http://dx.doi.org/10.1107/S1600536809055640
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AT jianfangfang bis22bipyridyldichloroacetatocopperiidichloroacetatedihydrate