2-Ethyl-6,6-ethyl­enedisulfanediyl-7-methoxy­methyl-1,2,3,4,5,6-hexa­hydro-1,5-methano­azocino[4,3-b]indol-3-one

The title compound, C(20)H(24)N(2)O(2)S(2), consists of a tetra­cyclic ring system containing an azocino skeleton with ethyl, dithiol­ane and methoxy­methyl groups as substituents. The benzene and five-membered rings are nearly coplanar, with a dihedral angle of 2.78 (11)°. The dithiol­ane ring adop...

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Detalles Bibliográficos
Autores principales: Tercan, Barış, Şahin, Ertan, Patır, Süleyman, Hökelek, Tuncer
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979738/
https://www.ncbi.nlm.nih.gov/pubmed/21579758
http://dx.doi.org/10.1107/S160053681000067X
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author Tercan, Barış
Şahin, Ertan
Patır, Süleyman
Hökelek, Tuncer
author_facet Tercan, Barış
Şahin, Ertan
Patır, Süleyman
Hökelek, Tuncer
author_sort Tercan, Barış
collection PubMed
description The title compound, C(20)H(24)N(2)O(2)S(2), consists of a tetra­cyclic ring system containing an azocino skeleton with ethyl, dithiol­ane and methoxy­methyl groups as substituents. The benzene and five-membered rings are nearly coplanar, with a dihedral angle of 2.78 (11)°. The dithiol­ane ring adopts an envelope conformation. In the crystal structure, inter­molecular C—H⋯O hydrogen bonds link the mol­ecules into chains nearly parallel to the c axis. Two C—H⋯π inter­actions are also present.
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spelling pubmed-29797382010-12-30 2-Ethyl-6,6-ethyl­enedisulfanediyl-7-methoxy­methyl-1,2,3,4,5,6-hexa­hydro-1,5-methano­azocino[4,3-b]indol-3-one Tercan, Barış Şahin, Ertan Patır, Süleyman Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(20)H(24)N(2)O(2)S(2), consists of a tetra­cyclic ring system containing an azocino skeleton with ethyl, dithiol­ane and methoxy­methyl groups as substituents. The benzene and five-membered rings are nearly coplanar, with a dihedral angle of 2.78 (11)°. The dithiol­ane ring adopts an envelope conformation. In the crystal structure, inter­molecular C—H⋯O hydrogen bonds link the mol­ecules into chains nearly parallel to the c axis. Two C—H⋯π inter­actions are also present. International Union of Crystallography 2010-01-09 /pmc/articles/PMC2979738/ /pubmed/21579758 http://dx.doi.org/10.1107/S160053681000067X Text en © Tercan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tercan, Barış
Şahin, Ertan
Patır, Süleyman
Hökelek, Tuncer
2-Ethyl-6,6-ethyl­enedisulfanediyl-7-methoxy­methyl-1,2,3,4,5,6-hexa­hydro-1,5-methano­azocino[4,3-b]indol-3-one
title 2-Ethyl-6,6-ethyl­enedisulfanediyl-7-methoxy­methyl-1,2,3,4,5,6-hexa­hydro-1,5-methano­azocino[4,3-b]indol-3-one
title_full 2-Ethyl-6,6-ethyl­enedisulfanediyl-7-methoxy­methyl-1,2,3,4,5,6-hexa­hydro-1,5-methano­azocino[4,3-b]indol-3-one
title_fullStr 2-Ethyl-6,6-ethyl­enedisulfanediyl-7-methoxy­methyl-1,2,3,4,5,6-hexa­hydro-1,5-methano­azocino[4,3-b]indol-3-one
title_full_unstemmed 2-Ethyl-6,6-ethyl­enedisulfanediyl-7-methoxy­methyl-1,2,3,4,5,6-hexa­hydro-1,5-methano­azocino[4,3-b]indol-3-one
title_short 2-Ethyl-6,6-ethyl­enedisulfanediyl-7-methoxy­methyl-1,2,3,4,5,6-hexa­hydro-1,5-methano­azocino[4,3-b]indol-3-one
title_sort 2-ethyl-6,6-ethyl­enedisulfanediyl-7-methoxy­methyl-1,2,3,4,5,6-hexa­hydro-1,5-methano­azocino[4,3-b]indol-3-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979738/
https://www.ncbi.nlm.nih.gov/pubmed/21579758
http://dx.doi.org/10.1107/S160053681000067X
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AT hokelektuncer 2ethyl66ethylenedisulfanediyl7methoxymethyl123456hexahydro15methanoazocino43bindol3one

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