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[μ-Bis(diphenylarsino)methane-1:2κ(2) As:As′]nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[diphenyl(phenylsulfanylmethyl)phosphine-3κP]-triangulo-triruthenium(0) chloroform hemisolvate
The asymmetric unit of the title triangulo-triruthenium cluster, [Ru(3)(C(25)H(22)As(2))(C(19)H(17)PS)(CO)(9)]·0.5CHCl(3), contains of one molecule of the triangulo-triruthenium complex and half a molecule of the disordered (two positions of equal weight) chloroform solvent. The bis(diphenylars...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979739/ https://www.ncbi.nlm.nih.gov/pubmed/21579685 http://dx.doi.org/10.1107/S1600536810001212 |
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author | Shawkataly, Omar bin Khan, Imthyaz Ahmed Yeap, Chin Sing Fun, Hoong-Kun |
author_facet | Shawkataly, Omar bin Khan, Imthyaz Ahmed Yeap, Chin Sing Fun, Hoong-Kun |
author_sort | Shawkataly, Omar bin |
collection | PubMed |
description | The asymmetric unit of the title triangulo-triruthenium cluster, [Ru(3)(C(25)H(22)As(2))(C(19)H(17)PS)(CO)(9)]·0.5CHCl(3), contains of one molecule of the triangulo-triruthenium complex and half a molecule of the disordered (two positions of equal weight) chloroform solvent. The bis(diphenylarsino)methane ligand bridges an Ru—Ru bond and the monodentate phosphine ligand bonds to the third Ru atom. Both the arsine and phosphine ligands are equatorial with respect to the Ru(3) triangle. In addition, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The benzene ring of phenylthiomethyl is disordered over two positions with refined site occupancies of 0.788 (11) and 0.212 (11). In the crystal packing, molecules are linked into chains along b axis by intermolecular C—H⋯O hydrogen bonds. Weak intermolecular C—H⋯π interactions further stabilize the crystal structure. |
format | Text |
id | pubmed-2979739 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29797392010-12-30 [μ-Bis(diphenylarsino)methane-1:2κ(2) As:As′]nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[diphenyl(phenylsulfanylmethyl)phosphine-3κP]-triangulo-triruthenium(0) chloroform hemisolvate Shawkataly, Omar bin Khan, Imthyaz Ahmed Yeap, Chin Sing Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title triangulo-triruthenium cluster, [Ru(3)(C(25)H(22)As(2))(C(19)H(17)PS)(CO)(9)]·0.5CHCl(3), contains of one molecule of the triangulo-triruthenium complex and half a molecule of the disordered (two positions of equal weight) chloroform solvent. The bis(diphenylarsino)methane ligand bridges an Ru—Ru bond and the monodentate phosphine ligand bonds to the third Ru atom. Both the arsine and phosphine ligands are equatorial with respect to the Ru(3) triangle. In addition, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The benzene ring of phenylthiomethyl is disordered over two positions with refined site occupancies of 0.788 (11) and 0.212 (11). In the crystal packing, molecules are linked into chains along b axis by intermolecular C—H⋯O hydrogen bonds. Weak intermolecular C—H⋯π interactions further stabilize the crystal structure. International Union of Crystallography 2010-01-30 /pmc/articles/PMC2979739/ /pubmed/21579685 http://dx.doi.org/10.1107/S1600536810001212 Text en © Shawkataly et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Shawkataly, Omar bin Khan, Imthyaz Ahmed Yeap, Chin Sing Fun, Hoong-Kun [μ-Bis(diphenylarsino)methane-1:2κ(2) As:As′]nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[diphenyl(phenylsulfanylmethyl)phosphine-3κP]-triangulo-triruthenium(0) chloroform hemisolvate |
title | [μ-Bis(diphenylarsino)methane-1:2κ(2)
As:As′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[diphenyl(phenylsulfanylmethyl)phosphine-3κP]-triangulo-triruthenium(0) chloroform hemisolvate |
title_full | [μ-Bis(diphenylarsino)methane-1:2κ(2)
As:As′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[diphenyl(phenylsulfanylmethyl)phosphine-3κP]-triangulo-triruthenium(0) chloroform hemisolvate |
title_fullStr | [μ-Bis(diphenylarsino)methane-1:2κ(2)
As:As′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[diphenyl(phenylsulfanylmethyl)phosphine-3κP]-triangulo-triruthenium(0) chloroform hemisolvate |
title_full_unstemmed | [μ-Bis(diphenylarsino)methane-1:2κ(2)
As:As′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[diphenyl(phenylsulfanylmethyl)phosphine-3κP]-triangulo-triruthenium(0) chloroform hemisolvate |
title_short | [μ-Bis(diphenylarsino)methane-1:2κ(2)
As:As′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[diphenyl(phenylsulfanylmethyl)phosphine-3κP]-triangulo-triruthenium(0) chloroform hemisolvate |
title_sort | [μ-bis(diphenylarsino)methane-1:2κ(2)
as:as′]nonacarbonyl-1κ(3)
c,2κ(3)
c,3κ(3)
c-[diphenyl(phenylsulfanylmethyl)phosphine-3κp]-triangulo-triruthenium(0) chloroform hemisolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979739/ https://www.ncbi.nlm.nih.gov/pubmed/21579685 http://dx.doi.org/10.1107/S1600536810001212 |
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