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[μ-Bis(diphenyl­arsino)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[diphen­yl(phenyl­sulfanylmeth­yl)phosphine-3κP]-triangulo-triruthenium(0) chloro­form hemisolvate

The asymmetric unit of the title triangulo-triruthenium cluster, [Ru(3)(C(25)H(22)As(2))(C(19)H(17)PS)(CO)(9)]·0.5CHCl(3), contains of one mol­ecule of the triangulo-triruthenium complex and half a mol­ecule of the disordered (two positions of equal weight) chloro­form solvent. The bis­(diphenyl­ars...

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Autores principales: Shawkataly, Omar bin, Khan, Imthyaz Ahmed, Yeap, Chin Sing, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979739/
https://www.ncbi.nlm.nih.gov/pubmed/21579685
http://dx.doi.org/10.1107/S1600536810001212
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author Shawkataly, Omar bin
Khan, Imthyaz Ahmed
Yeap, Chin Sing
Fun, Hoong-Kun
author_facet Shawkataly, Omar bin
Khan, Imthyaz Ahmed
Yeap, Chin Sing
Fun, Hoong-Kun
author_sort Shawkataly, Omar bin
collection PubMed
description The asymmetric unit of the title triangulo-triruthenium cluster, [Ru(3)(C(25)H(22)As(2))(C(19)H(17)PS)(CO)(9)]·0.5CHCl(3), contains of one mol­ecule of the triangulo-triruthenium complex and half a mol­ecule of the disordered (two positions of equal weight) chloro­form solvent. The bis­(diphenyl­arsino)methane ligand bridges an Ru—Ru bond and the monodentate phosphine ligand bonds to the third Ru atom. Both the arsine and phosphine ligands are equatorial with respect to the Ru(3) triangle. In addition, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The benzene ring of phenyl­thio­methyl is disordered over two positions with refined site occupancies of 0.788 (11) and 0.212 (11). In the crystal packing, mol­ecules are linked into chains along b axis by inter­molecular C—H⋯O hydrogen bonds. Weak inter­molecular C—H⋯π inter­actions further stabilize the crystal structure.
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spelling pubmed-29797392010-12-30 [μ-Bis(diphenyl­arsino)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[diphen­yl(phenyl­sulfanylmeth­yl)phosphine-3κP]-triangulo-triruthenium(0) chloro­form hemisolvate Shawkataly, Omar bin Khan, Imthyaz Ahmed Yeap, Chin Sing Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title triangulo-triruthenium cluster, [Ru(3)(C(25)H(22)As(2))(C(19)H(17)PS)(CO)(9)]·0.5CHCl(3), contains of one mol­ecule of the triangulo-triruthenium complex and half a mol­ecule of the disordered (two positions of equal weight) chloro­form solvent. The bis­(diphenyl­arsino)methane ligand bridges an Ru—Ru bond and the monodentate phosphine ligand bonds to the third Ru atom. Both the arsine and phosphine ligands are equatorial with respect to the Ru(3) triangle. In addition, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The benzene ring of phenyl­thio­methyl is disordered over two positions with refined site occupancies of 0.788 (11) and 0.212 (11). In the crystal packing, mol­ecules are linked into chains along b axis by inter­molecular C—H⋯O hydrogen bonds. Weak inter­molecular C—H⋯π inter­actions further stabilize the crystal structure. International Union of Crystallography 2010-01-30 /pmc/articles/PMC2979739/ /pubmed/21579685 http://dx.doi.org/10.1107/S1600536810001212 Text en © Shawkataly et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shawkataly, Omar bin
Khan, Imthyaz Ahmed
Yeap, Chin Sing
Fun, Hoong-Kun
[μ-Bis(diphenyl­arsino)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[diphen­yl(phenyl­sulfanylmeth­yl)phosphine-3κP]-triangulo-triruthenium(0) chloro­form hemisolvate
title [μ-Bis(diphenyl­arsino)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[diphen­yl(phenyl­sulfanylmeth­yl)phosphine-3κP]-triangulo-triruthenium(0) chloro­form hemisolvate
title_full [μ-Bis(diphenyl­arsino)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[diphen­yl(phenyl­sulfanylmeth­yl)phosphine-3κP]-triangulo-triruthenium(0) chloro­form hemisolvate
title_fullStr [μ-Bis(diphenyl­arsino)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[diphen­yl(phenyl­sulfanylmeth­yl)phosphine-3κP]-triangulo-triruthenium(0) chloro­form hemisolvate
title_full_unstemmed [μ-Bis(diphenyl­arsino)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[diphen­yl(phenyl­sulfanylmeth­yl)phosphine-3κP]-triangulo-triruthenium(0) chloro­form hemisolvate
title_short [μ-Bis(diphenyl­arsino)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[diphen­yl(phenyl­sulfanylmeth­yl)phosphine-3κP]-triangulo-triruthenium(0) chloro­form hemisolvate
title_sort [μ-bis(diphenyl­arsino)methane-1:2κ(2) as:as′]nona­carbonyl-1κ(3) c,2κ(3) c,3κ(3) c-[diphen­yl(phenyl­sulfanylmeth­yl)phosphine-3κp]-triangulo-triruthenium(0) chloro­form hemisolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979739/
https://www.ncbi.nlm.nih.gov/pubmed/21579685
http://dx.doi.org/10.1107/S1600536810001212
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