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N-(5-Amino-2-methyl­phen­yl)-4-(3-pyri­dyl)­pyrimidin-2-amine

The title compound, C(16)H(15)N(5), crystallizes with two independent mol­ecules (A and B) in the asymmetric unit. The dihedral angles of the pyrimidine ring with the benzene and pyridyl rings are 22.3 (1) and 53.2 (9)°, respectively, in mol­ecule A, and 6.8 (1) and 11.6 (9)° in mol­ecule B. The cry...

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Detalles Bibliográficos
Autores principales: Jasinski, Jerry P., Butcher, Ray J., Hakim Al-Arique, Q. N. M., Yathirajan, H. S., Narayana, B.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979750/
https://www.ncbi.nlm.nih.gov/pubmed/21579776
http://dx.doi.org/10.1107/S1600536810000899
Descripción
Sumario:The title compound, C(16)H(15)N(5), crystallizes with two independent mol­ecules (A and B) in the asymmetric unit. The dihedral angles of the pyrimidine ring with the benzene and pyridyl rings are 22.3 (1) and 53.2 (9)°, respectively, in mol­ecule A, and 6.8 (1) and 11.6 (9)° in mol­ecule B. The crystal packing is influenced by the collective action of weak inter­molecular N—H⋯N hydrogen bonds, a π–π stacking inter­action between neighbouring pyridyl rings of mol­ecule A [centroid–centroid distance = 3.8395 (10) Å] and C—H⋯π inter­actions.