(Bis{2-[3-(2,4,6-trimethyl­benz­yl)imid­azolin-2-yliden-1-yl-κC (2)]-4-methyl­phenyl}amido-κN)chloridopalladium(II)

The coordination geometry about the Pd centre in the title compound, [Pd(C(40)H(42)N(5))Cl], is approximately square-planar. The CNC pincer-type N-heterocyclic carbene ligand binds to the Pd atom in a tridentate fashion by the amido N atom and the two carbene atoms and generates two six-membered che...

Descripción completa

Detalles Bibliográficos
Autores principales: Cheng, Guan-Jun, Wei, Wei, Zhou, Chuang, Luo, Mei-Ming
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979753/
https://www.ncbi.nlm.nih.gov/pubmed/21579662
http://dx.doi.org/10.1107/S1600536810002382
_version_ 1782191491058237440
author Cheng, Guan-Jun
Wei, Wei
Zhou, Chuang
Luo, Mei-Ming
author_facet Cheng, Guan-Jun
Wei, Wei
Zhou, Chuang
Luo, Mei-Ming
author_sort Cheng, Guan-Jun
collection PubMed
description The coordination geometry about the Pd centre in the title compound, [Pd(C(40)H(42)N(5))Cl], is approximately square-planar. The CNC pincer-type N-heterocyclic carbene ligand binds to the Pd atom in a tridentate fashion by the amido N atom and the two carbene atoms and generates two six-membered chelate rings, completing the coordination.
format Text
id pubmed-2979753
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29797532010-12-30 (Bis{2-[3-(2,4,6-trimethyl­benz­yl)imid­azolin-2-yliden-1-yl-κC (2)]-4-methyl­phenyl}amido-κN)chloridopalladium(II) Cheng, Guan-Jun Wei, Wei Zhou, Chuang Luo, Mei-Ming Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The coordination geometry about the Pd centre in the title compound, [Pd(C(40)H(42)N(5))Cl], is approximately square-planar. The CNC pincer-type N-heterocyclic carbene ligand binds to the Pd atom in a tridentate fashion by the amido N atom and the two carbene atoms and generates two six-membered chelate rings, completing the coordination. International Union of Crystallography 2010-01-23 /pmc/articles/PMC2979753/ /pubmed/21579662 http://dx.doi.org/10.1107/S1600536810002382 Text en © Cheng et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cheng, Guan-Jun
Wei, Wei
Zhou, Chuang
Luo, Mei-Ming
(Bis{2-[3-(2,4,6-trimethyl­benz­yl)imid­azolin-2-yliden-1-yl-κC (2)]-4-methyl­phenyl}amido-κN)chloridopalladium(II)
title (Bis{2-[3-(2,4,6-trimethyl­benz­yl)imid­azolin-2-yliden-1-yl-κC (2)]-4-methyl­phenyl}amido-κN)chloridopalladium(II)
title_full (Bis{2-[3-(2,4,6-trimethyl­benz­yl)imid­azolin-2-yliden-1-yl-κC (2)]-4-methyl­phenyl}amido-κN)chloridopalladium(II)
title_fullStr (Bis{2-[3-(2,4,6-trimethyl­benz­yl)imid­azolin-2-yliden-1-yl-κC (2)]-4-methyl­phenyl}amido-κN)chloridopalladium(II)
title_full_unstemmed (Bis{2-[3-(2,4,6-trimethyl­benz­yl)imid­azolin-2-yliden-1-yl-κC (2)]-4-methyl­phenyl}amido-κN)chloridopalladium(II)
title_short (Bis{2-[3-(2,4,6-trimethyl­benz­yl)imid­azolin-2-yliden-1-yl-κC (2)]-4-methyl­phenyl}amido-κN)chloridopalladium(II)
title_sort (bis{2-[3-(2,4,6-trimethyl­benz­yl)imid­azolin-2-yliden-1-yl-κc (2)]-4-methyl­phenyl}amido-κn)chloridopalladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979753/
https://www.ncbi.nlm.nih.gov/pubmed/21579662
http://dx.doi.org/10.1107/S1600536810002382
work_keys_str_mv AT chengguanjun bis23246trimethylbenzylimidazolin2yliden1ylkc24methylphenylamidoknchloridopalladiumii
AT weiwei bis23246trimethylbenzylimidazolin2yliden1ylkc24methylphenylamidoknchloridopalladiumii
AT zhouchuang bis23246trimethylbenzylimidazolin2yliden1ylkc24methylphenylamidoknchloridopalladiumii
AT luomeiming bis23246trimethylbenzylimidazolin2yliden1ylkc24methylphenylamidoknchloridopalladiumii

Ejemplares similares