Cargando…

{2-[(2-Acetyl­hydrazin-1-yl­idene)methyl-κ(2) N (1),O]-6-methoxy­phenolato-κO (1)}(nitrato-κO)copper(II) monohydrate

In the title complex, [Cu(C(10)H(11)N(2)O(3))(NO(3))]·H(2)O, prepared from the Schiff base N′-(3-meth­oxy-2-oxidobenzyl­idene)­acetohydrazide, the Cu(II) atom is coordinated by two O atoms and one N atom from the ligand and one O atom from a nitrate group in a distorted square-planar geometry. The C...

Descripción completa

Detalles Bibliográficos
Autores principales: Thiam, Ibrahima Elhadj, Retailleau, Pascal, Navaza, Alda, Gaye, Mohamed
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979759/
https://www.ncbi.nlm.nih.gov/pubmed/21579618
http://dx.doi.org/10.1107/S1600536810000632
Descripción
Sumario:In the title complex, [Cu(C(10)H(11)N(2)O(3))(NO(3))]·H(2)O, prepared from the Schiff base N′-(3-meth­oxy-2-oxidobenzyl­idene)­acetohydrazide, the Cu(II) atom is coordinated by two O atoms and one N atom from the ligand and one O atom from a nitrate group in a distorted square-planar geometry. The Cu(II) atom has a weak inter­action with another O atom of the nitrate group. The two O atoms of the tridentate Schiff base ligand are in a trans arrangement. O—H⋯O and N—H⋯O hydrogen bonds involving the uncoordinated water mol­ecule are observed.