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{2-[(2-Acetylhydrazin-1-ylidene)methyl-κ(2) N (1),O]-6-methoxyphenolato-κO (1)}(nitrato-κO)copper(II) monohydrate
In the title complex, [Cu(C(10)H(11)N(2)O(3))(NO(3))]·H(2)O, prepared from the Schiff base N′-(3-methoxy-2-oxidobenzylidene)acetohydrazide, the Cu(II) atom is coordinated by two O atoms and one N atom from the ligand and one O atom from a nitrate group in a distorted square-planar geometry. The C...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979759/ https://www.ncbi.nlm.nih.gov/pubmed/21579618 http://dx.doi.org/10.1107/S1600536810000632 |
Sumario: | In the title complex, [Cu(C(10)H(11)N(2)O(3))(NO(3))]·H(2)O, prepared from the Schiff base N′-(3-methoxy-2-oxidobenzylidene)acetohydrazide, the Cu(II) atom is coordinated by two O atoms and one N atom from the ligand and one O atom from a nitrate group in a distorted square-planar geometry. The Cu(II) atom has a weak interaction with another O atom of the nitrate group. The two O atoms of the tridentate Schiff base ligand are in a trans arrangement. O—H⋯O and N—H⋯O hydrogen bonds involving the uncoordinated water molecule are observed. |
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