{2-[(2-Acetyl­hydrazin-1-yl­idene)methyl-κ(2) N (1),O]-6-methoxy­phenolato-κO (1)}(nitrato-κO)copper(II) monohydrate

In the title complex, [Cu(C(10)H(11)N(2)O(3))(NO(3))]·H(2)O, prepared from the Schiff base N′-(3-meth­oxy-2-oxidobenzyl­idene)­acetohydrazide, the Cu(II) atom is coordinated by two O atoms and one N atom from the ligand and one O atom from a nitrate group in a distorted square-planar geometry. The C...

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Detalles Bibliográficos
Autores principales: Thiam, Ibrahima Elhadj, Retailleau, Pascal, Navaza, Alda, Gaye, Mohamed
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979759/
https://www.ncbi.nlm.nih.gov/pubmed/21579618
http://dx.doi.org/10.1107/S1600536810000632
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author Thiam, Ibrahima Elhadj
Retailleau, Pascal
Navaza, Alda
Gaye, Mohamed
author_facet Thiam, Ibrahima Elhadj
Retailleau, Pascal
Navaza, Alda
Gaye, Mohamed
author_sort Thiam, Ibrahima Elhadj
collection PubMed
description In the title complex, [Cu(C(10)H(11)N(2)O(3))(NO(3))]·H(2)O, prepared from the Schiff base N′-(3-meth­oxy-2-oxidobenzyl­idene)­acetohydrazide, the Cu(II) atom is coordinated by two O atoms and one N atom from the ligand and one O atom from a nitrate group in a distorted square-planar geometry. The Cu(II) atom has a weak inter­action with another O atom of the nitrate group. The two O atoms of the tridentate Schiff base ligand are in a trans arrangement. O—H⋯O and N—H⋯O hydrogen bonds involving the uncoordinated water mol­ecule are observed.
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spelling pubmed-29797592010-12-30 {2-[(2-Acetyl­hydrazin-1-yl­idene)methyl-κ(2) N (1),O]-6-methoxy­phenolato-κO (1)}(nitrato-κO)copper(II) monohydrate Thiam, Ibrahima Elhadj Retailleau, Pascal Navaza, Alda Gaye, Mohamed Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(10)H(11)N(2)O(3))(NO(3))]·H(2)O, prepared from the Schiff base N′-(3-meth­oxy-2-oxidobenzyl­idene)­acetohydrazide, the Cu(II) atom is coordinated by two O atoms and one N atom from the ligand and one O atom from a nitrate group in a distorted square-planar geometry. The Cu(II) atom has a weak inter­action with another O atom of the nitrate group. The two O atoms of the tridentate Schiff base ligand are in a trans arrangement. O—H⋯O and N—H⋯O hydrogen bonds involving the uncoordinated water mol­ecule are observed. International Union of Crystallography 2010-01-09 /pmc/articles/PMC2979759/ /pubmed/21579618 http://dx.doi.org/10.1107/S1600536810000632 Text en © Thiam et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Thiam, Ibrahima Elhadj
Retailleau, Pascal
Navaza, Alda
Gaye, Mohamed
{2-[(2-Acetyl­hydrazin-1-yl­idene)methyl-κ(2) N (1),O]-6-methoxy­phenolato-κO (1)}(nitrato-κO)copper(II) monohydrate
title {2-[(2-Acetyl­hydrazin-1-yl­idene)methyl-κ(2) N (1),O]-6-methoxy­phenolato-κO (1)}(nitrato-κO)copper(II) monohydrate
title_full {2-[(2-Acetyl­hydrazin-1-yl­idene)methyl-κ(2) N (1),O]-6-methoxy­phenolato-κO (1)}(nitrato-κO)copper(II) monohydrate
title_fullStr {2-[(2-Acetyl­hydrazin-1-yl­idene)methyl-κ(2) N (1),O]-6-methoxy­phenolato-κO (1)}(nitrato-κO)copper(II) monohydrate
title_full_unstemmed {2-[(2-Acetyl­hydrazin-1-yl­idene)methyl-κ(2) N (1),O]-6-methoxy­phenolato-κO (1)}(nitrato-κO)copper(II) monohydrate
title_short {2-[(2-Acetyl­hydrazin-1-yl­idene)methyl-κ(2) N (1),O]-6-methoxy­phenolato-κO (1)}(nitrato-κO)copper(II) monohydrate
title_sort {2-[(2-acetyl­hydrazin-1-yl­idene)methyl-κ(2) n (1),o]-6-methoxy­phenolato-κo (1)}(nitrato-κo)copper(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979759/
https://www.ncbi.nlm.nih.gov/pubmed/21579618
http://dx.doi.org/10.1107/S1600536810000632
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