1-Bromo­methyl-4-aza-1-azoniabicyclo­[2.2.2]octane bromide

The title compound, C(7)H(14)BrN(2) (+)·Br(−), was prepared by nucleophilic substitution of DABCO (systematic name: 1,4-diaza­bicyclo­[2.2.2]octa­ne) with dibromo­methane in acetone. The structure features Br⋯H close contacts (2.79 and 2.90 Å) as well as a weak bromine–bromide inter­action [3.6625 (...

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Detalles Bibliográficos
Autores principales: Finke, Aaron D., Gray, Danielle L., Moore, Jeffrey S.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979768/
https://www.ncbi.nlm.nih.gov/pubmed/21579799
http://dx.doi.org/10.1107/S1600536810000292
Descripción
Sumario:The title compound, C(7)H(14)BrN(2) (+)·Br(−), was prepared by nucleophilic substitution of DABCO (systematic name: 1,4-diaza­bicyclo­[2.2.2]octa­ne) with dibromo­methane in acetone. The structure features Br⋯H close contacts (2.79 and 2.90 Å) as well as a weak bromine–bromide inter­action [3.6625 (6) Å].

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