1-Bromo­methyl-4-aza-1-azoniabicyclo­[2.2.2]octane bromide

The title compound, C(7)H(14)BrN(2) (+)·Br(−), was prepared by nucleophilic substitution of DABCO (systematic name: 1,4-diaza­bicyclo­[2.2.2]octa­ne) with dibromo­methane in acetone. The structure features Br⋯H close contacts (2.79 and 2.90 Å) as well as a weak bromine–bromide inter­action [3.6625 (...

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Detalles Bibliográficos
Autores principales: Finke, Aaron D., Gray, Danielle L., Moore, Jeffrey S.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979768/
https://www.ncbi.nlm.nih.gov/pubmed/21579799
http://dx.doi.org/10.1107/S1600536810000292
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author Finke, Aaron D.
Gray, Danielle L.
Moore, Jeffrey S.
author_facet Finke, Aaron D.
Gray, Danielle L.
Moore, Jeffrey S.
author_sort Finke, Aaron D.
collection PubMed
description The title compound, C(7)H(14)BrN(2) (+)·Br(−), was prepared by nucleophilic substitution of DABCO (systematic name: 1,4-diaza­bicyclo­[2.2.2]octa­ne) with dibromo­methane in acetone. The structure features Br⋯H close contacts (2.79 and 2.90 Å) as well as a weak bromine–bromide inter­action [3.6625 (6) Å].
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spelling pubmed-29797682010-12-30 1-Bromo­methyl-4-aza-1-azoniabicyclo­[2.2.2]octane bromide Finke, Aaron D. Gray, Danielle L. Moore, Jeffrey S. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(7)H(14)BrN(2) (+)·Br(−), was prepared by nucleophilic substitution of DABCO (systematic name: 1,4-diaza­bicyclo­[2.2.2]octa­ne) with dibromo­methane in acetone. The structure features Br⋯H close contacts (2.79 and 2.90 Å) as well as a weak bromine–bromide inter­action [3.6625 (6) Å]. International Union of Crystallography 2010-01-16 /pmc/articles/PMC2979768/ /pubmed/21579799 http://dx.doi.org/10.1107/S1600536810000292 Text en © Finke et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Finke, Aaron D.
Gray, Danielle L.
Moore, Jeffrey S.
1-Bromo­methyl-4-aza-1-azoniabicyclo­[2.2.2]octane bromide
title 1-Bromo­methyl-4-aza-1-azoniabicyclo­[2.2.2]octane bromide
title_full 1-Bromo­methyl-4-aza-1-azoniabicyclo­[2.2.2]octane bromide
title_fullStr 1-Bromo­methyl-4-aza-1-azoniabicyclo­[2.2.2]octane bromide
title_full_unstemmed 1-Bromo­methyl-4-aza-1-azoniabicyclo­[2.2.2]octane bromide
title_short 1-Bromo­methyl-4-aza-1-azoniabicyclo­[2.2.2]octane bromide
title_sort 1-bromo­methyl-4-aza-1-azoniabicyclo­[2.2.2]octane bromide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979768/
https://www.ncbi.nlm.nih.gov/pubmed/21579799
http://dx.doi.org/10.1107/S1600536810000292
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AT graydaniellel 1bromomethyl4aza1azoniabicyclo222octanebromide
AT moorejeffreys 1bromomethyl4aza1azoniabicyclo222octanebromide

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