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Dichlorido[N,N-diethyl-N′-(2-pyridylmethylene)ethane-1,2-diamine]mercury(II)
The Hg atom in the title compound, [HgCl(2)(C(12)H(19)N(3))], adopts a distorted trigonal-bipyramidal geometry, being ligated by two Cl atoms and three N atoms of the N,N-diethyl-N′-(2-pyridylmethylene)ethane-1,2-diamine ligand. The dihedral angle between the HgN(3) and HgCl(2 )least-squares planes...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979770/ https://www.ncbi.nlm.nih.gov/pubmed/21579610 http://dx.doi.org/10.1107/S1600536810000103 |
| _version_ | 1782191495617445888 |
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| author | Kim, Young-Inn Seo, Hoe-Joo Kim, Ji-Hoon Lee, You-Soon Kang, Sung Kwon |
| author_facet | Kim, Young-Inn Seo, Hoe-Joo Kim, Ji-Hoon Lee, You-Soon Kang, Sung Kwon |
| author_sort | Kim, Young-Inn |
| collection | PubMed |
| description | The Hg atom in the title compound, [HgCl(2)(C(12)H(19)N(3))], adopts a distorted trigonal-bipyramidal geometry, being ligated by two Cl atoms and three N atoms of the N,N-diethyl-N′-(2-pyridylmethylene)ethane-1,2-diamine ligand. The dihedral angle between the HgN(3) and HgCl(2 )least-squares planes is 88.6 (1)°. The Hg—N distances including the pyridine N and the ammonium N atom are about 0.20 Å longer than the Hg—N distance including the imino N atom. |
| format | Text |
| id | pubmed-2979770 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29797702010-12-30 Dichlorido[N,N-diethyl-N′-(2-pyridylmethylene)ethane-1,2-diamine]mercury(II) Kim, Young-Inn Seo, Hoe-Joo Kim, Ji-Hoon Lee, You-Soon Kang, Sung Kwon Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Hg atom in the title compound, [HgCl(2)(C(12)H(19)N(3))], adopts a distorted trigonal-bipyramidal geometry, being ligated by two Cl atoms and three N atoms of the N,N-diethyl-N′-(2-pyridylmethylene)ethane-1,2-diamine ligand. The dihedral angle between the HgN(3) and HgCl(2 )least-squares planes is 88.6 (1)°. The Hg—N distances including the pyridine N and the ammonium N atom are about 0.20 Å longer than the Hg—N distance including the imino N atom. International Union of Crystallography 2010-01-09 /pmc/articles/PMC2979770/ /pubmed/21579610 http://dx.doi.org/10.1107/S1600536810000103 Text en © Kim et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Kim, Young-Inn Seo, Hoe-Joo Kim, Ji-Hoon Lee, You-Soon Kang, Sung Kwon Dichlorido[N,N-diethyl-N′-(2-pyridylmethylene)ethane-1,2-diamine]mercury(II) |
| title | Dichlorido[N,N-diethyl-N′-(2-pyridylmethylene)ethane-1,2-diamine]mercury(II) |
| title_full | Dichlorido[N,N-diethyl-N′-(2-pyridylmethylene)ethane-1,2-diamine]mercury(II) |
| title_fullStr | Dichlorido[N,N-diethyl-N′-(2-pyridylmethylene)ethane-1,2-diamine]mercury(II) |
| title_full_unstemmed | Dichlorido[N,N-diethyl-N′-(2-pyridylmethylene)ethane-1,2-diamine]mercury(II) |
| title_short | Dichlorido[N,N-diethyl-N′-(2-pyridylmethylene)ethane-1,2-diamine]mercury(II) |
| title_sort | dichlorido[n,n-diethyl-n′-(2-pyridylmethylene)ethane-1,2-diamine]mercury(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979770/ https://www.ncbi.nlm.nih.gov/pubmed/21579610 http://dx.doi.org/10.1107/S1600536810000103 |
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