(1R,3aR,5aS,6S,8aR,8bR,9aS)-1-Hydr­oxy-6-isopropyl-1,3a,5a-trimethyl­perhydro­cyclo­penta­[a]cyclo­propa[i]naphthalen-4-one

The title compound (also know as azorellanone), C(20)H(32)O(2), is built up from three fused carbocycles, one five-membered ring and two six-membered rings. The five membered-ring has an envelope conformation, whereas the six-membered rings have a distorted half-chair and a twist–boat conformation....

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Detalles Bibliográficos
Autores principales: Brito, Iván, Bórquez, Jorge, Loyola, Luis Alberto, Bolte, Michael, Albanez, Joselyn
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979771/
https://www.ncbi.nlm.nih.gov/pubmed/21579782
http://dx.doi.org/10.1107/S1600536810001169
Descripción
Sumario:The title compound (also know as azorellanone), C(20)H(32)O(2), is built up from three fused carbocycles, one five-membered ring and two six-membered rings. The five membered-ring has an envelope conformation, whereas the six-membered rings have a distorted half-chair and a twist–boat conformation. In the crystal, mol­ecules are linked by O—H⋯O inter­actions into zigzag chains with graph-set notation C(8) along [010]. The absolute configuration was assigned on the basis of earlier chemical studies.

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