(1R,3aR,5aS,6S,8aR,8bR,9aS)-1-Hydr­oxy-6-isopropyl-1,3a,5a-trimethyl­perhydro­cyclo­penta­[a]cyclo­propa[i]naphthalen-4-one

The title compound (also know as azorellanone), C(20)H(32)O(2), is built up from three fused carbocycles, one five-membered ring and two six-membered rings. The five membered-ring has an envelope conformation, whereas the six-membered rings have a distorted half-chair and a twist–boat conformation....

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Detalles Bibliográficos
Autores principales: Brito, Iván, Bórquez, Jorge, Loyola, Luis Alberto, Bolte, Michael, Albanez, Joselyn
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979771/
https://www.ncbi.nlm.nih.gov/pubmed/21579782
http://dx.doi.org/10.1107/S1600536810001169
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author Brito, Iván
Bórquez, Jorge
Loyola, Luis Alberto
Bolte, Michael
Albanez, Joselyn
author_facet Brito, Iván
Bórquez, Jorge
Loyola, Luis Alberto
Bolte, Michael
Albanez, Joselyn
author_sort Brito, Iván
collection PubMed
description The title compound (also know as azorellanone), C(20)H(32)O(2), is built up from three fused carbocycles, one five-membered ring and two six-membered rings. The five membered-ring has an envelope conformation, whereas the six-membered rings have a distorted half-chair and a twist–boat conformation. In the crystal, mol­ecules are linked by O—H⋯O inter­actions into zigzag chains with graph-set notation C(8) along [010]. The absolute configuration was assigned on the basis of earlier chemical studies.
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spelling pubmed-29797712010-12-30 (1R,3aR,5aS,6S,8aR,8bR,9aS)-1-Hydr­oxy-6-isopropyl-1,3a,5a-trimethyl­perhydro­cyclo­penta­[a]cyclo­propa[i]naphthalen-4-one Brito, Iván Bórquez, Jorge Loyola, Luis Alberto Bolte, Michael Albanez, Joselyn Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound (also know as azorellanone), C(20)H(32)O(2), is built up from three fused carbocycles, one five-membered ring and two six-membered rings. The five membered-ring has an envelope conformation, whereas the six-membered rings have a distorted half-chair and a twist–boat conformation. In the crystal, mol­ecules are linked by O—H⋯O inter­actions into zigzag chains with graph-set notation C(8) along [010]. The absolute configuration was assigned on the basis of earlier chemical studies. International Union of Crystallography 2010-01-16 /pmc/articles/PMC2979771/ /pubmed/21579782 http://dx.doi.org/10.1107/S1600536810001169 Text en © Brito et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Brito, Iván
Bórquez, Jorge
Loyola, Luis Alberto
Bolte, Michael
Albanez, Joselyn
(1R,3aR,5aS,6S,8aR,8bR,9aS)-1-Hydr­oxy-6-isopropyl-1,3a,5a-trimethyl­perhydro­cyclo­penta­[a]cyclo­propa[i]naphthalen-4-one
title (1R,3aR,5aS,6S,8aR,8bR,9aS)-1-Hydr­oxy-6-isopropyl-1,3a,5a-trimethyl­perhydro­cyclo­penta­[a]cyclo­propa[i]naphthalen-4-one
title_full (1R,3aR,5aS,6S,8aR,8bR,9aS)-1-Hydr­oxy-6-isopropyl-1,3a,5a-trimethyl­perhydro­cyclo­penta­[a]cyclo­propa[i]naphthalen-4-one
title_fullStr (1R,3aR,5aS,6S,8aR,8bR,9aS)-1-Hydr­oxy-6-isopropyl-1,3a,5a-trimethyl­perhydro­cyclo­penta­[a]cyclo­propa[i]naphthalen-4-one
title_full_unstemmed (1R,3aR,5aS,6S,8aR,8bR,9aS)-1-Hydr­oxy-6-isopropyl-1,3a,5a-trimethyl­perhydro­cyclo­penta­[a]cyclo­propa[i]naphthalen-4-one
title_short (1R,3aR,5aS,6S,8aR,8bR,9aS)-1-Hydr­oxy-6-isopropyl-1,3a,5a-trimethyl­perhydro­cyclo­penta­[a]cyclo­propa[i]naphthalen-4-one
title_sort (1r,3ar,5as,6s,8ar,8br,9as)-1-hydr­oxy-6-isopropyl-1,3a,5a-trimethyl­perhydro­cyclo­penta­[a]cyclo­propa[i]naphthalen-4-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979771/
https://www.ncbi.nlm.nih.gov/pubmed/21579782
http://dx.doi.org/10.1107/S1600536810001169
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