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Bis{[μ-bis(diphenylarsino)methane-1:2κ(2) As:As′]nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris(4-methoxyphenyl)arsine-3κAs]-triangulo-triruthenium(0)} dichloromethane solvate
The asymmetric unit of the title triangulo-triruthenium compound, 2[Ru(3)(C(25)H(22)As(2))(C(21)H(21)AsO(3))(CO)(9)]·CH(2)Cl(2), contains one triangulo-triruthenium complex molecule and one half of the dichloromethane solvent. The dichloromethane solvent lies across a crystallographic inversion c...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979775/ https://www.ncbi.nlm.nih.gov/pubmed/21579650 http://dx.doi.org/10.1107/S160053680905315X |
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author | Shawkataly, Omar bin Khan, Imthyaz Ahmed Yeap, Chin Sing Fun, Hoong-Kun |
author_facet | Shawkataly, Omar bin Khan, Imthyaz Ahmed Yeap, Chin Sing Fun, Hoong-Kun |
author_sort | Shawkataly, Omar bin |
collection | PubMed |
description | The asymmetric unit of the title triangulo-triruthenium compound, 2[Ru(3)(C(25)H(22)As(2))(C(21)H(21)AsO(3))(CO)(9)]·CH(2)Cl(2), contains one triangulo-triruthenium complex molecule and one half of the dichloromethane solvent. The dichloromethane solvent lies across a crystallographic inversion center leading to the molecule being disordered over two positions of equal occupancy. The bis(diphenylarsino)methane ligand bridges an Ru—Ru bond and the monodentate arsine ligand bonds to the third Ru atom. Both the arsine ligands are equatorial with respect to the Ru(3) triangle. In addition, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The trimethoxyphenylarsino benzene rings make dihedral angles of 83.01 (8), 65.81 (8) and 76.20 (8)° with each other. The dihedral angles between the two benzene rings are 82.69 (9) and 78.83 (9)° for the two diphenylarsino groups. In the crystal packing, the molecules are stacked along the a axis and weak intermolecular C—H⋯π interactions stabilize the crystal structure. |
format | Text |
id | pubmed-2979775 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29797752010-12-30 Bis{[μ-bis(diphenylarsino)methane-1:2κ(2) As:As′]nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris(4-methoxyphenyl)arsine-3κAs]-triangulo-triruthenium(0)} dichloromethane solvate Shawkataly, Omar bin Khan, Imthyaz Ahmed Yeap, Chin Sing Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title triangulo-triruthenium compound, 2[Ru(3)(C(25)H(22)As(2))(C(21)H(21)AsO(3))(CO)(9)]·CH(2)Cl(2), contains one triangulo-triruthenium complex molecule and one half of the dichloromethane solvent. The dichloromethane solvent lies across a crystallographic inversion center leading to the molecule being disordered over two positions of equal occupancy. The bis(diphenylarsino)methane ligand bridges an Ru—Ru bond and the monodentate arsine ligand bonds to the third Ru atom. Both the arsine ligands are equatorial with respect to the Ru(3) triangle. In addition, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The trimethoxyphenylarsino benzene rings make dihedral angles of 83.01 (8), 65.81 (8) and 76.20 (8)° with each other. The dihedral angles between the two benzene rings are 82.69 (9) and 78.83 (9)° for the two diphenylarsino groups. In the crystal packing, the molecules are stacked along the a axis and weak intermolecular C—H⋯π interactions stabilize the crystal structure. International Union of Crystallography 2010-01-16 /pmc/articles/PMC2979775/ /pubmed/21579650 http://dx.doi.org/10.1107/S160053680905315X Text en © Shawkataly et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Shawkataly, Omar bin Khan, Imthyaz Ahmed Yeap, Chin Sing Fun, Hoong-Kun Bis{[μ-bis(diphenylarsino)methane-1:2κ(2) As:As′]nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris(4-methoxyphenyl)arsine-3κAs]-triangulo-triruthenium(0)} dichloromethane solvate |
title | Bis{[μ-bis(diphenylarsino)methane-1:2κ(2)
As:As′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[tris(4-methoxyphenyl)arsine-3κAs]-triangulo-triruthenium(0)} dichloromethane solvate |
title_full | Bis{[μ-bis(diphenylarsino)methane-1:2κ(2)
As:As′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[tris(4-methoxyphenyl)arsine-3κAs]-triangulo-triruthenium(0)} dichloromethane solvate |
title_fullStr | Bis{[μ-bis(diphenylarsino)methane-1:2κ(2)
As:As′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[tris(4-methoxyphenyl)arsine-3κAs]-triangulo-triruthenium(0)} dichloromethane solvate |
title_full_unstemmed | Bis{[μ-bis(diphenylarsino)methane-1:2κ(2)
As:As′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[tris(4-methoxyphenyl)arsine-3κAs]-triangulo-triruthenium(0)} dichloromethane solvate |
title_short | Bis{[μ-bis(diphenylarsino)methane-1:2κ(2)
As:As′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[tris(4-methoxyphenyl)arsine-3κAs]-triangulo-triruthenium(0)} dichloromethane solvate |
title_sort | bis{[μ-bis(diphenylarsino)methane-1:2κ(2)
as:as′]nonacarbonyl-1κ(3)
c,2κ(3)
c,3κ(3)
c-[tris(4-methoxyphenyl)arsine-3κas]-triangulo-triruthenium(0)} dichloromethane solvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979775/ https://www.ncbi.nlm.nih.gov/pubmed/21579650 http://dx.doi.org/10.1107/S160053680905315X |
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