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Bis{[μ-bis­(diphenyl­arsino)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris­(4-methoxy­phen­yl)arsine-3κAs]-triangulo-triruthenium(0)} dichloro­methane solvate

The asymmetric unit of the title triangulo-triruthenium compound, 2[Ru(3)(C(25)H(22)As(2))(C(21)H(21)AsO(3))(CO)(9)]·CH(2)Cl(2), contains one triangulo-triruthenium complex mol­ecule and one half of the dichloro­methane solvent. The dichloro­methane solvent lies across a crystallographic inversion c...

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Autores principales: Shawkataly, Omar bin, Khan, Imthyaz Ahmed, Yeap, Chin Sing, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979775/
https://www.ncbi.nlm.nih.gov/pubmed/21579650
http://dx.doi.org/10.1107/S160053680905315X
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author Shawkataly, Omar bin
Khan, Imthyaz Ahmed
Yeap, Chin Sing
Fun, Hoong-Kun
author_facet Shawkataly, Omar bin
Khan, Imthyaz Ahmed
Yeap, Chin Sing
Fun, Hoong-Kun
author_sort Shawkataly, Omar bin
collection PubMed
description The asymmetric unit of the title triangulo-triruthenium compound, 2[Ru(3)(C(25)H(22)As(2))(C(21)H(21)AsO(3))(CO)(9)]·CH(2)Cl(2), contains one triangulo-triruthenium complex mol­ecule and one half of the dichloro­methane solvent. The dichloro­methane solvent lies across a crystallographic inversion center leading to the mol­ecule being disordered over two positions of equal occupancy. The bis­(diphenyl­arsino)methane ligand bridges an Ru—Ru bond and the monodentate arsine ligand bonds to the third Ru atom. Both the arsine ligands are equatorial with respect to the Ru(3) triangle. In addition, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The trimethoxy­phenyl­arsino benzene rings make dihedral angles of 83.01 (8), 65.81 (8) and 76.20 (8)° with each other. The dihedral angles between the two benzene rings are 82.69 (9) and 78.83 (9)° for the two diphenyl­arsino groups. In the crystal packing, the mol­ecules are stacked along the a axis and weak inter­molecular C—H⋯π inter­actions stabilize the crystal structure.
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spelling pubmed-29797752010-12-30 Bis{[μ-bis­(diphenyl­arsino)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris­(4-methoxy­phen­yl)arsine-3κAs]-triangulo-triruthenium(0)} dichloro­methane solvate Shawkataly, Omar bin Khan, Imthyaz Ahmed Yeap, Chin Sing Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title triangulo-triruthenium compound, 2[Ru(3)(C(25)H(22)As(2))(C(21)H(21)AsO(3))(CO)(9)]·CH(2)Cl(2), contains one triangulo-triruthenium complex mol­ecule and one half of the dichloro­methane solvent. The dichloro­methane solvent lies across a crystallographic inversion center leading to the mol­ecule being disordered over two positions of equal occupancy. The bis­(diphenyl­arsino)methane ligand bridges an Ru—Ru bond and the monodentate arsine ligand bonds to the third Ru atom. Both the arsine ligands are equatorial with respect to the Ru(3) triangle. In addition, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The trimethoxy­phenyl­arsino benzene rings make dihedral angles of 83.01 (8), 65.81 (8) and 76.20 (8)° with each other. The dihedral angles between the two benzene rings are 82.69 (9) and 78.83 (9)° for the two diphenyl­arsino groups. In the crystal packing, the mol­ecules are stacked along the a axis and weak inter­molecular C—H⋯π inter­actions stabilize the crystal structure. International Union of Crystallography 2010-01-16 /pmc/articles/PMC2979775/ /pubmed/21579650 http://dx.doi.org/10.1107/S160053680905315X Text en © Shawkataly et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shawkataly, Omar bin
Khan, Imthyaz Ahmed
Yeap, Chin Sing
Fun, Hoong-Kun
Bis{[μ-bis­(diphenyl­arsino)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris­(4-methoxy­phen­yl)arsine-3κAs]-triangulo-triruthenium(0)} dichloro­methane solvate
title Bis{[μ-bis­(diphenyl­arsino)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris­(4-methoxy­phen­yl)arsine-3κAs]-triangulo-triruthenium(0)} dichloro­methane solvate
title_full Bis{[μ-bis­(diphenyl­arsino)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris­(4-methoxy­phen­yl)arsine-3κAs]-triangulo-triruthenium(0)} dichloro­methane solvate
title_fullStr Bis{[μ-bis­(diphenyl­arsino)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris­(4-methoxy­phen­yl)arsine-3κAs]-triangulo-triruthenium(0)} dichloro­methane solvate
title_full_unstemmed Bis{[μ-bis­(diphenyl­arsino)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris­(4-methoxy­phen­yl)arsine-3κAs]-triangulo-triruthenium(0)} dichloro­methane solvate
title_short Bis{[μ-bis­(diphenyl­arsino)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris­(4-methoxy­phen­yl)arsine-3κAs]-triangulo-triruthenium(0)} dichloro­methane solvate
title_sort bis{[μ-bis­(diphenyl­arsino)methane-1:2κ(2) as:as′]nona­carbonyl-1κ(3) c,2κ(3) c,3κ(3) c-[tris­(4-methoxy­phen­yl)arsine-3κas]-triangulo-triruthenium(0)} dichloro­methane solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979775/
https://www.ncbi.nlm.nih.gov/pubmed/21579650
http://dx.doi.org/10.1107/S160053680905315X
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