Chloridobis[2-(1,5-dimethyl-1H-pyrazol-3-yl-κN (2))-1-methyl-1H-imidazole-κN (3)]copper(II) chloride methanol hemisolvate tetra­hydrate

In the title compound, [CuCl(C(9)H(12)N(4))(2)]Cl·0.5CH(3)OH·4H(2)O, the Cu(II) ion adopts a distorted trigonal-bipyramidal coordination arising from two bidentate ligands and a Cl(−) anion. The two heterocyclic ligands are planar with dihedral angles of 3.4 (1) and 0.7 (1)° between the pyrazole and...

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Detalles Bibliográficos
Autores principales: El Ghayati, Lhoussaine, Tjiou, El Mostafa, El Ammari, Lahcen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979776/
https://www.ncbi.nlm.nih.gov/pubmed/21579617
http://dx.doi.org/10.1107/S1600536810000048
Descripción
Sumario:In the title compound, [CuCl(C(9)H(12)N(4))(2)]Cl·0.5CH(3)OH·4H(2)O, the Cu(II) ion adopts a distorted trigonal-bipyramidal coordination arising from two bidentate ligands and a Cl(−) anion. The two heterocyclic ligands are planar with dihedral angles of 3.4 (1) and 0.7 (1)° between the pyrazole and imidazole rings. In the crystal, water mol­ecules and uncoordinated chloride anions form an O—H⋯Cl and O—H⋯O hydrogen-bonded sheet parallel to (100) which lies between two layers of complex mol­ecules. The packing is further stabilized by C—H⋯Cl and C—H⋯O hydrogen bonds. The methanol solvent mol­ecule is disordered across a centre of inversion.

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