Chloridobis[2-(1,5-dimethyl-1H-pyrazol-3-yl-κN (2))-1-methyl-1H-imidazole-κN (3)]copper(II) chloride methanol hemisolvate tetra­hydrate

In the title compound, [CuCl(C(9)H(12)N(4))(2)]Cl·0.5CH(3)OH·4H(2)O, the Cu(II) ion adopts a distorted trigonal-bipyramidal coordination arising from two bidentate ligands and a Cl(−) anion. The two heterocyclic ligands are planar with dihedral angles of 3.4 (1) and 0.7 (1)° between the pyrazole and...

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Detalles Bibliográficos
Autores principales: El Ghayati, Lhoussaine, Tjiou, El Mostafa, El Ammari, Lahcen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979776/
https://www.ncbi.nlm.nih.gov/pubmed/21579617
http://dx.doi.org/10.1107/S1600536810000048
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author El Ghayati, Lhoussaine
Tjiou, El Mostafa
El Ammari, Lahcen
author_facet El Ghayati, Lhoussaine
Tjiou, El Mostafa
El Ammari, Lahcen
author_sort El Ghayati, Lhoussaine
collection PubMed
description In the title compound, [CuCl(C(9)H(12)N(4))(2)]Cl·0.5CH(3)OH·4H(2)O, the Cu(II) ion adopts a distorted trigonal-bipyramidal coordination arising from two bidentate ligands and a Cl(−) anion. The two heterocyclic ligands are planar with dihedral angles of 3.4 (1) and 0.7 (1)° between the pyrazole and imidazole rings. In the crystal, water mol­ecules and uncoordinated chloride anions form an O—H⋯Cl and O—H⋯O hydrogen-bonded sheet parallel to (100) which lies between two layers of complex mol­ecules. The packing is further stabilized by C—H⋯Cl and C—H⋯O hydrogen bonds. The methanol solvent mol­ecule is disordered across a centre of inversion.
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spelling pubmed-29797762010-12-30 Chloridobis[2-(1,5-dimethyl-1H-pyrazol-3-yl-κN (2))-1-methyl-1H-imidazole-κN (3)]copper(II) chloride methanol hemisolvate tetra­hydrate El Ghayati, Lhoussaine Tjiou, El Mostafa El Ammari, Lahcen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CuCl(C(9)H(12)N(4))(2)]Cl·0.5CH(3)OH·4H(2)O, the Cu(II) ion adopts a distorted trigonal-bipyramidal coordination arising from two bidentate ligands and a Cl(−) anion. The two heterocyclic ligands are planar with dihedral angles of 3.4 (1) and 0.7 (1)° between the pyrazole and imidazole rings. In the crystal, water mol­ecules and uncoordinated chloride anions form an O—H⋯Cl and O—H⋯O hydrogen-bonded sheet parallel to (100) which lies between two layers of complex mol­ecules. The packing is further stabilized by C—H⋯Cl and C—H⋯O hydrogen bonds. The methanol solvent mol­ecule is disordered across a centre of inversion. International Union of Crystallography 2010-01-09 /pmc/articles/PMC2979776/ /pubmed/21579617 http://dx.doi.org/10.1107/S1600536810000048 Text en © El Ghayati et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
El Ghayati, Lhoussaine
Tjiou, El Mostafa
El Ammari, Lahcen
Chloridobis[2-(1,5-dimethyl-1H-pyrazol-3-yl-κN (2))-1-methyl-1H-imidazole-κN (3)]copper(II) chloride methanol hemisolvate tetra­hydrate
title Chloridobis[2-(1,5-dimethyl-1H-pyrazol-3-yl-κN (2))-1-methyl-1H-imidazole-κN (3)]copper(II) chloride methanol hemisolvate tetra­hydrate
title_full Chloridobis[2-(1,5-dimethyl-1H-pyrazol-3-yl-κN (2))-1-methyl-1H-imidazole-κN (3)]copper(II) chloride methanol hemisolvate tetra­hydrate
title_fullStr Chloridobis[2-(1,5-dimethyl-1H-pyrazol-3-yl-κN (2))-1-methyl-1H-imidazole-κN (3)]copper(II) chloride methanol hemisolvate tetra­hydrate
title_full_unstemmed Chloridobis[2-(1,5-dimethyl-1H-pyrazol-3-yl-κN (2))-1-methyl-1H-imidazole-κN (3)]copper(II) chloride methanol hemisolvate tetra­hydrate
title_short Chloridobis[2-(1,5-dimethyl-1H-pyrazol-3-yl-κN (2))-1-methyl-1H-imidazole-κN (3)]copper(II) chloride methanol hemisolvate tetra­hydrate
title_sort chloridobis[2-(1,5-dimethyl-1h-pyrazol-3-yl-κn (2))-1-methyl-1h-imidazole-κn (3)]copper(ii) chloride methanol hemisolvate tetra­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979776/
https://www.ncbi.nlm.nih.gov/pubmed/21579617
http://dx.doi.org/10.1107/S1600536810000048
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AT tjiouelmostafa chloridobis215dimethyl1hpyrazol3ylkn21methyl1himidazolekn3copperiichloridemethanolhemisolvatetetrahydrate
AT elammarilahcen chloridobis215dimethyl1hpyrazol3ylkn21methyl1himidazolekn3copperiichloridemethanolhemisolvatetetrahydrate

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