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Redetermination of aqua(dihydrogen ethylenediaminetetraacetato-κ(5) O,O′,N,N′,O′′)nickel(II)
The crystal structure of the title compound, [Ni(C(10)H(14)N(2)O(8))(H(2)O)] or [Ni(H(2)edta)(H(2)O)] (H(4)edta is ethylenediaminetetraacetic acid), originally determined by Smith & Hoard [J. Am. Chem. Soc. (1959), 81, 556–561] has been redetermined to a significantly higher precision. The N...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979777/ https://www.ncbi.nlm.nih.gov/pubmed/21579661 http://dx.doi.org/10.1107/S1600536810002011 |
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| author | Kočanová, Ivana Kuchár, Juraj Dankovičová, Vladimíra Černák, Juraj |
| author_facet | Kočanová, Ivana Kuchár, Juraj Dankovičová, Vladimíra Černák, Juraj |
| author_sort | Kočanová, Ivana |
| collection | PubMed |
| description | The crystal structure of the title compound, [Ni(C(10)H(14)N(2)O(8))(H(2)O)] or [Ni(H(2)edta)(H(2)O)] (H(4)edta is ethylenediaminetetraacetic acid), originally determined by Smith & Hoard [J. Am. Chem. Soc. (1959), 81, 556–561] has been redetermined to a significantly higher precision. The Ni(II) atom is coordinated in a distorted octahedral geometry by two N atoms and three O atoms from three carboxylate groups of the H(2)edta(2−) ligand and by an O atom of a water molecule. The complex molecules are linked by intermolecular O—H⋯O hydrogen bonds into layers perpendicular to [100]. |
| format | Text |
| id | pubmed-2979777 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29797772010-12-30 Redetermination of aqua(dihydrogen ethylenediaminetetraacetato-κ(5) O,O′,N,N′,O′′)nickel(II) Kočanová, Ivana Kuchár, Juraj Dankovičová, Vladimíra Černák, Juraj Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, [Ni(C(10)H(14)N(2)O(8))(H(2)O)] or [Ni(H(2)edta)(H(2)O)] (H(4)edta is ethylenediaminetetraacetic acid), originally determined by Smith & Hoard [J. Am. Chem. Soc. (1959), 81, 556–561] has been redetermined to a significantly higher precision. The Ni(II) atom is coordinated in a distorted octahedral geometry by two N atoms and three O atoms from three carboxylate groups of the H(2)edta(2−) ligand and by an O atom of a water molecule. The complex molecules are linked by intermolecular O—H⋯O hydrogen bonds into layers perpendicular to [100]. International Union of Crystallography 2010-01-23 /pmc/articles/PMC2979777/ /pubmed/21579661 http://dx.doi.org/10.1107/S1600536810002011 Text en © Kočanová et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Kočanová, Ivana Kuchár, Juraj Dankovičová, Vladimíra Černák, Juraj Redetermination of aqua(dihydrogen ethylenediaminetetraacetato-κ(5) O,O′,N,N′,O′′)nickel(II) |
| title | Redetermination of aqua(dihydrogen ethylenediaminetetraacetato-κ(5)
O,O′,N,N′,O′′)nickel(II) |
| title_full | Redetermination of aqua(dihydrogen ethylenediaminetetraacetato-κ(5)
O,O′,N,N′,O′′)nickel(II) |
| title_fullStr | Redetermination of aqua(dihydrogen ethylenediaminetetraacetato-κ(5)
O,O′,N,N′,O′′)nickel(II) |
| title_full_unstemmed | Redetermination of aqua(dihydrogen ethylenediaminetetraacetato-κ(5)
O,O′,N,N′,O′′)nickel(II) |
| title_short | Redetermination of aqua(dihydrogen ethylenediaminetetraacetato-κ(5)
O,O′,N,N′,O′′)nickel(II) |
| title_sort | redetermination of aqua(dihydrogen ethylenediaminetetraacetato-κ(5)
o,o′,n,n′,o′′)nickel(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979777/ https://www.ncbi.nlm.nih.gov/pubmed/21579661 http://dx.doi.org/10.1107/S1600536810002011 |
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