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[μ-Bis(diphenylarsino)methane-1:2κ(2) As:As′][bis(4-methoxyphenyl)phenylphosphine-3κP]-nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-triangulo-triruthenium(0) dichloromethane 0.15-solvate
The asymmetric unit of the title triangulo-triruthenium compound, [Ru(3)(C(25)H(22)As(2))(C(20)H(19)O(2)P)(CO)(9)]·0.15CH(2)Cl(2), contains one molecule of the triangulo-triruthenium complex and one partially occupied dichloromethane solvent molecule. The dichloromethane solvent lies across a cr...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979782/ https://www.ncbi.nlm.nih.gov/pubmed/21579684 http://dx.doi.org/10.1107/S1600536810001194 |
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author | Shawkataly, Omar bin Khan, Imthyaz Ahmed Yeap, Chin Sing Fun, Hoong-Kun |
author_facet | Shawkataly, Omar bin Khan, Imthyaz Ahmed Yeap, Chin Sing Fun, Hoong-Kun |
author_sort | Shawkataly, Omar bin |
collection | PubMed |
description | The asymmetric unit of the title triangulo-triruthenium compound, [Ru(3)(C(25)H(22)As(2))(C(20)H(19)O(2)P)(CO)(9)]·0.15CH(2)Cl(2), contains one molecule of the triangulo-triruthenium complex and one partially occupied dichloromethane solvent molecule. The dichloromethane solvent lies across a crystallographic inversion center leading to the molecule being disordered over two positions of equal occupancy. The bis(diphenylarsino)methane ligand bridges an Ru—Ru bond and the monodentate arsine ligand bonds to the third Ru atom. Both the arsine ligands are equatorial with respect to the Ru(3) triangle. In addition, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three phosphorus-bound benzene rings make dihedral angles of 72.7 (3), 80.9 (3) and 70.8 (2)° with each other. The dihedral angles between the two benzene rings are 79.9 (3) and 81.5 (2)° for the two diphenylarsino groups. |
format | Text |
id | pubmed-2979782 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29797822010-12-30 [μ-Bis(diphenylarsino)methane-1:2κ(2) As:As′][bis(4-methoxyphenyl)phenylphosphine-3κP]-nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-triangulo-triruthenium(0) dichloromethane 0.15-solvate Shawkataly, Omar bin Khan, Imthyaz Ahmed Yeap, Chin Sing Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title triangulo-triruthenium compound, [Ru(3)(C(25)H(22)As(2))(C(20)H(19)O(2)P)(CO)(9)]·0.15CH(2)Cl(2), contains one molecule of the triangulo-triruthenium complex and one partially occupied dichloromethane solvent molecule. The dichloromethane solvent lies across a crystallographic inversion center leading to the molecule being disordered over two positions of equal occupancy. The bis(diphenylarsino)methane ligand bridges an Ru—Ru bond and the monodentate arsine ligand bonds to the third Ru atom. Both the arsine ligands are equatorial with respect to the Ru(3) triangle. In addition, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three phosphorus-bound benzene rings make dihedral angles of 72.7 (3), 80.9 (3) and 70.8 (2)° with each other. The dihedral angles between the two benzene rings are 79.9 (3) and 81.5 (2)° for the two diphenylarsino groups. International Union of Crystallography 2010-01-30 /pmc/articles/PMC2979782/ /pubmed/21579684 http://dx.doi.org/10.1107/S1600536810001194 Text en © Shawkataly et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Shawkataly, Omar bin Khan, Imthyaz Ahmed Yeap, Chin Sing Fun, Hoong-Kun [μ-Bis(diphenylarsino)methane-1:2κ(2) As:As′][bis(4-methoxyphenyl)phenylphosphine-3κP]-nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-triangulo-triruthenium(0) dichloromethane 0.15-solvate |
title | [μ-Bis(diphenylarsino)methane-1:2κ(2)
As:As′][bis(4-methoxyphenyl)phenylphosphine-3κP]-nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-triangulo-triruthenium(0) dichloromethane 0.15-solvate |
title_full | [μ-Bis(diphenylarsino)methane-1:2κ(2)
As:As′][bis(4-methoxyphenyl)phenylphosphine-3κP]-nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-triangulo-triruthenium(0) dichloromethane 0.15-solvate |
title_fullStr | [μ-Bis(diphenylarsino)methane-1:2κ(2)
As:As′][bis(4-methoxyphenyl)phenylphosphine-3κP]-nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-triangulo-triruthenium(0) dichloromethane 0.15-solvate |
title_full_unstemmed | [μ-Bis(diphenylarsino)methane-1:2κ(2)
As:As′][bis(4-methoxyphenyl)phenylphosphine-3κP]-nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-triangulo-triruthenium(0) dichloromethane 0.15-solvate |
title_short | [μ-Bis(diphenylarsino)methane-1:2κ(2)
As:As′][bis(4-methoxyphenyl)phenylphosphine-3κP]-nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-triangulo-triruthenium(0) dichloromethane 0.15-solvate |
title_sort | [μ-bis(diphenylarsino)methane-1:2κ(2)
as:as′][bis(4-methoxyphenyl)phenylphosphine-3κp]-nonacarbonyl-1κ(3)
c,2κ(3)
c,3κ(3)
c-triangulo-triruthenium(0) dichloromethane 0.15-solvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979782/ https://www.ncbi.nlm.nih.gov/pubmed/21579684 http://dx.doi.org/10.1107/S1600536810001194 |
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