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Guanidinium chlorochromate
In the title compound, guanidinium chloridotrioxidochromate(VI), (CH(6)N(3))[CrClO(3)], both the cation and anion are generated by crystallographic mirror symmetry, with one O and one N atom and the Cr, Cl and C atoms lying on the mirror plane. The bond lengths in the guanidinium cation are interm...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979783/ https://www.ncbi.nlm.nih.gov/pubmed/21579667 http://dx.doi.org/10.1107/S1600536810002710 |
Sumario: | In the title compound, guanidinium chloridotrioxidochromate(VI), (CH(6)N(3))[CrClO(3)], both the cation and anion are generated by crystallographic mirror symmetry, with one O and one N atom and the Cr, Cl and C atoms lying on the mirror plane. The bond lengths in the guanidinium cation are intermediate between normal C—N and C=N bond lengths, indicating significant delocalization in this species. In the crystal structure, intermolecular N—H⋯Cl interactions generate R (2) (1)(6) ring motifs. These ring motifs are further interconnected by intermolecular N—H⋯O hydrogen bonds into infinite chains along [010]. |
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