Guanidinium chloro­chromate

In the title compound, guanidinium chloridotrioxidochrom­ate(VI), (CH(6)N(3))[CrClO(3)], both the cation and anion are generated by crystallographic mirror symmetry, with one O and one N atom and the Cr, Cl and C atoms lying on the mirror plane. The bond lengths in the guanidinium cation are inter­m...

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Autores principales: Fun, Hoong-Kun, Goh, Jia Hao, Kar, Arnab, Goswami, Shyamaprosad
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979783/
https://www.ncbi.nlm.nih.gov/pubmed/21579667
http://dx.doi.org/10.1107/S1600536810002710
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author Fun, Hoong-Kun
Goh, Jia Hao
Kar, Arnab
Goswami, Shyamaprosad
author_facet Fun, Hoong-Kun
Goh, Jia Hao
Kar, Arnab
Goswami, Shyamaprosad
author_sort Fun, Hoong-Kun
collection PubMed
description In the title compound, guanidinium chloridotrioxidochrom­ate(VI), (CH(6)N(3))[CrClO(3)], both the cation and anion are generated by crystallographic mirror symmetry, with one O and one N atom and the Cr, Cl and C atoms lying on the mirror plane. The bond lengths in the guanidinium cation are inter­mediate between normal C—N and C=N bond lengths, indicating significant delocalization in this species. In the crystal structure, inter­molecular N—H⋯Cl inter­actions generate R (2) (1)(6) ring motifs. These ring motifs are further inter­connected by inter­molecular N—H⋯O hydrogen bonds into infinite chains along [010].
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spelling pubmed-29797832010-12-30 Guanidinium chloro­chromate Fun, Hoong-Kun Goh, Jia Hao Kar, Arnab Goswami, Shyamaprosad Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, guanidinium chloridotrioxidochrom­ate(VI), (CH(6)N(3))[CrClO(3)], both the cation and anion are generated by crystallographic mirror symmetry, with one O and one N atom and the Cr, Cl and C atoms lying on the mirror plane. The bond lengths in the guanidinium cation are inter­mediate between normal C—N and C=N bond lengths, indicating significant delocalization in this species. In the crystal structure, inter­molecular N—H⋯Cl inter­actions generate R (2) (1)(6) ring motifs. These ring motifs are further inter­connected by inter­molecular N—H⋯O hydrogen bonds into infinite chains along [010]. International Union of Crystallography 2010-01-27 /pmc/articles/PMC2979783/ /pubmed/21579667 http://dx.doi.org/10.1107/S1600536810002710 Text en © Fun et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fun, Hoong-Kun
Goh, Jia Hao
Kar, Arnab
Goswami, Shyamaprosad
Guanidinium chloro­chromate
title Guanidinium chloro­chromate
title_full Guanidinium chloro­chromate
title_fullStr Guanidinium chloro­chromate
title_full_unstemmed Guanidinium chloro­chromate
title_short Guanidinium chloro­chromate
title_sort guanidinium chloro­chromate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979783/
https://www.ncbi.nlm.nih.gov/pubmed/21579667
http://dx.doi.org/10.1107/S1600536810002710
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AT gohjiahao guanidiniumchlorochromate
AT kararnab guanidiniumchlorochromate
AT goswamishyamaprosad guanidiniumchlorochromate

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