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4,4-Bis(1H-pyrrol-2-yl)penta­nol

The title achiral compound, C(13)H(18)N(2)O, crystallized in the chiral monoclinic space group P2(1). The pyrrole rings are inclined to one another by 62.30 (11)°, and the propanol chain is in an extended conformation. In the crystal, the two pyrrole NH groups are involved in inter­molecular N—H⋯O h...

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Detalles Bibliográficos
Autores principales: Journot, Guillaume, Neier, Reinhard, Stoeckli-Evans, Helen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979789/
https://www.ncbi.nlm.nih.gov/pubmed/21579814
http://dx.doi.org/10.1107/S1600536809054269
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author Journot, Guillaume
Neier, Reinhard
Stoeckli-Evans, Helen
author_facet Journot, Guillaume
Neier, Reinhard
Stoeckli-Evans, Helen
author_sort Journot, Guillaume
collection PubMed
description The title achiral compound, C(13)H(18)N(2)O, crystallized in the chiral monoclinic space group P2(1). The pyrrole rings are inclined to one another by 62.30 (11)°, and the propanol chain is in an extended conformation. In the crystal, the two pyrrole NH groups are involved in inter­molecular N—H⋯O hydrogen bonds, leading to the formation of a helical arrangement propagating along the b axis. An inter­esting feature of the crystal structure is the absence of any conventional hydrogen bonds involving the hydr­oxy H atom. There is, however, a weak inter­molecular O—H⋯π inter­action involving one of the pyrrole rings.
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spelling pubmed-29797892010-12-30 4,4-Bis(1H-pyrrol-2-yl)penta­nol Journot, Guillaume Neier, Reinhard Stoeckli-Evans, Helen Acta Crystallogr Sect E Struct Rep Online Organic Papers The title achiral compound, C(13)H(18)N(2)O, crystallized in the chiral monoclinic space group P2(1). The pyrrole rings are inclined to one another by 62.30 (11)°, and the propanol chain is in an extended conformation. In the crystal, the two pyrrole NH groups are involved in inter­molecular N—H⋯O hydrogen bonds, leading to the formation of a helical arrangement propagating along the b axis. An inter­esting feature of the crystal structure is the absence of any conventional hydrogen bonds involving the hydr­oxy H atom. There is, however, a weak inter­molecular O—H⋯π inter­action involving one of the pyrrole rings. International Union of Crystallography 2010-01-16 /pmc/articles/PMC2979789/ /pubmed/21579814 http://dx.doi.org/10.1107/S1600536809054269 Text en © Journot et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Journot, Guillaume
Neier, Reinhard
Stoeckli-Evans, Helen
4,4-Bis(1H-pyrrol-2-yl)penta­nol
title 4,4-Bis(1H-pyrrol-2-yl)penta­nol
title_full 4,4-Bis(1H-pyrrol-2-yl)penta­nol
title_fullStr 4,4-Bis(1H-pyrrol-2-yl)penta­nol
title_full_unstemmed 4,4-Bis(1H-pyrrol-2-yl)penta­nol
title_short 4,4-Bis(1H-pyrrol-2-yl)penta­nol
title_sort 4,4-bis(1h-pyrrol-2-yl)penta­nol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979789/
https://www.ncbi.nlm.nih.gov/pubmed/21579814
http://dx.doi.org/10.1107/S1600536809054269
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