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4,4-Bis(1H-pyrrol-2-yl)pentanol
The title achiral compound, C(13)H(18)N(2)O, crystallized in the chiral monoclinic space group P2(1). The pyrrole rings are inclined to one another by 62.30 (11)°, and the propanol chain is in an extended conformation. In the crystal, the two pyrrole NH groups are involved in intermolecular N—H⋯O h...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979789/ https://www.ncbi.nlm.nih.gov/pubmed/21579814 http://dx.doi.org/10.1107/S1600536809054269 |
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author | Journot, Guillaume Neier, Reinhard Stoeckli-Evans, Helen |
author_facet | Journot, Guillaume Neier, Reinhard Stoeckli-Evans, Helen |
author_sort | Journot, Guillaume |
collection | PubMed |
description | The title achiral compound, C(13)H(18)N(2)O, crystallized in the chiral monoclinic space group P2(1). The pyrrole rings are inclined to one another by 62.30 (11)°, and the propanol chain is in an extended conformation. In the crystal, the two pyrrole NH groups are involved in intermolecular N—H⋯O hydrogen bonds, leading to the formation of a helical arrangement propagating along the b axis. An interesting feature of the crystal structure is the absence of any conventional hydrogen bonds involving the hydroxy H atom. There is, however, a weak intermolecular O—H⋯π interaction involving one of the pyrrole rings. |
format | Text |
id | pubmed-2979789 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29797892010-12-30 4,4-Bis(1H-pyrrol-2-yl)pentanol Journot, Guillaume Neier, Reinhard Stoeckli-Evans, Helen Acta Crystallogr Sect E Struct Rep Online Organic Papers The title achiral compound, C(13)H(18)N(2)O, crystallized in the chiral monoclinic space group P2(1). The pyrrole rings are inclined to one another by 62.30 (11)°, and the propanol chain is in an extended conformation. In the crystal, the two pyrrole NH groups are involved in intermolecular N—H⋯O hydrogen bonds, leading to the formation of a helical arrangement propagating along the b axis. An interesting feature of the crystal structure is the absence of any conventional hydrogen bonds involving the hydroxy H atom. There is, however, a weak intermolecular O—H⋯π interaction involving one of the pyrrole rings. International Union of Crystallography 2010-01-16 /pmc/articles/PMC2979789/ /pubmed/21579814 http://dx.doi.org/10.1107/S1600536809054269 Text en © Journot et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Journot, Guillaume Neier, Reinhard Stoeckli-Evans, Helen 4,4-Bis(1H-pyrrol-2-yl)pentanol |
title | 4,4-Bis(1H-pyrrol-2-yl)pentanol |
title_full | 4,4-Bis(1H-pyrrol-2-yl)pentanol |
title_fullStr | 4,4-Bis(1H-pyrrol-2-yl)pentanol |
title_full_unstemmed | 4,4-Bis(1H-pyrrol-2-yl)pentanol |
title_short | 4,4-Bis(1H-pyrrol-2-yl)pentanol |
title_sort | 4,4-bis(1h-pyrrol-2-yl)pentanol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979789/ https://www.ncbi.nlm.nih.gov/pubmed/21579814 http://dx.doi.org/10.1107/S1600536809054269 |
work_keys_str_mv | AT journotguillaume 44bis1hpyrrol2ylpentanol AT neierreinhard 44bis1hpyrrol2ylpentanol AT stoecklievanshelen 44bis1hpyrrol2ylpentanol |