Poly[tetra-μ-cyanido-dipyridine­cadmium(II)zinc(II)]

In the title coordination polymer, [CdZn(CN)(4)(C(5)H(5)N)(2)](n), the Zn(II) atom (site symmetry 222) adopts a distorted ZnC(4) tetra­hedral geometry, being coordinated by four crystallographically equivalent cyanide ions. The cyanide ion bridges to a Cd(II) centre via its N atom. The Cd atom (site...

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Detalles Bibliográficos
Autores principales: Li, Sheng, Tang, Kun, Zhang, Fu-Li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979792/
https://www.ncbi.nlm.nih.gov/pubmed/21579598
http://dx.doi.org/10.1107/S1600536809054579
Descripción
Sumario:In the title coordination polymer, [CdZn(CN)(4)(C(5)H(5)N)(2)](n), the Zn(II) atom (site symmetry 222) adopts a distorted ZnC(4) tetra­hedral geometry, being coordinated by four crystallographically equivalent cyanide ions. The cyanide ion bridges to a Cd(II) centre via its N atom. The Cd atom (site symmetry 2/m) coordination is a distorted CdN(6) octa­hedron, arising from four cyanide N atoms and two pyridine N atoms. The complete pyridine mol­ecule is generated by m symmetry, with the N atom and one C atom lying on the reflecting plane. In the crystal, the bridging cyanide ions result in a three-dimensional network.

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