Poly[tetra-μ-cyanido-dipyridine­cadmium(II)zinc(II)]

In the title coordination polymer, [CdZn(CN)(4)(C(5)H(5)N)(2)](n), the Zn(II) atom (site symmetry 222) adopts a distorted ZnC(4) tetra­hedral geometry, being coordinated by four crystallographically equivalent cyanide ions. The cyanide ion bridges to a Cd(II) centre via its N atom. The Cd atom (site...

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Detalles Bibliográficos
Autores principales: Li, Sheng, Tang, Kun, Zhang, Fu-Li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979792/
https://www.ncbi.nlm.nih.gov/pubmed/21579598
http://dx.doi.org/10.1107/S1600536809054579
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author Li, Sheng
Tang, Kun
Zhang, Fu-Li
author_facet Li, Sheng
Tang, Kun
Zhang, Fu-Li
author_sort Li, Sheng
collection PubMed
description In the title coordination polymer, [CdZn(CN)(4)(C(5)H(5)N)(2)](n), the Zn(II) atom (site symmetry 222) adopts a distorted ZnC(4) tetra­hedral geometry, being coordinated by four crystallographically equivalent cyanide ions. The cyanide ion bridges to a Cd(II) centre via its N atom. The Cd atom (site symmetry 2/m) coordination is a distorted CdN(6) octa­hedron, arising from four cyanide N atoms and two pyridine N atoms. The complete pyridine mol­ecule is generated by m symmetry, with the N atom and one C atom lying on the reflecting plane. In the crystal, the bridging cyanide ions result in a three-dimensional network.
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spelling pubmed-29797922010-12-30 Poly[tetra-μ-cyanido-dipyridine­cadmium(II)zinc(II)] Li, Sheng Tang, Kun Zhang, Fu-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [CdZn(CN)(4)(C(5)H(5)N)(2)](n), the Zn(II) atom (site symmetry 222) adopts a distorted ZnC(4) tetra­hedral geometry, being coordinated by four crystallographically equivalent cyanide ions. The cyanide ion bridges to a Cd(II) centre via its N atom. The Cd atom (site symmetry 2/m) coordination is a distorted CdN(6) octa­hedron, arising from four cyanide N atoms and two pyridine N atoms. The complete pyridine mol­ecule is generated by m symmetry, with the N atom and one C atom lying on the reflecting plane. In the crystal, the bridging cyanide ions result in a three-dimensional network. International Union of Crystallography 2010-01-09 /pmc/articles/PMC2979792/ /pubmed/21579598 http://dx.doi.org/10.1107/S1600536809054579 Text en © Li et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Sheng
Tang, Kun
Zhang, Fu-Li
Poly[tetra-μ-cyanido-dipyridine­cadmium(II)zinc(II)]
title Poly[tetra-μ-cyanido-dipyridine­cadmium(II)zinc(II)]
title_full Poly[tetra-μ-cyanido-dipyridine­cadmium(II)zinc(II)]
title_fullStr Poly[tetra-μ-cyanido-dipyridine­cadmium(II)zinc(II)]
title_full_unstemmed Poly[tetra-μ-cyanido-dipyridine­cadmium(II)zinc(II)]
title_short Poly[tetra-μ-cyanido-dipyridine­cadmium(II)zinc(II)]
title_sort poly[tetra-μ-cyanido-dipyridine­cadmium(ii)zinc(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979792/
https://www.ncbi.nlm.nih.gov/pubmed/21579598
http://dx.doi.org/10.1107/S1600536809054579
work_keys_str_mv AT lisheng polytetramcyanidodipyridinecadmiumiizincii
AT tangkun polytetramcyanidodipyridinecadmiumiizincii
AT zhangfuli polytetramcyanidodipyridinecadmiumiizincii

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