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Methanoldioxido{1-[(2RS)-(2-oxidopropyl)iminomethyl]-2-naphtholato}molybdenium(VI)
Crystals of the title compound, [Mo(C(14)H(13)NO(2))O(2)(CH(4)O)], were obtained by recrystallization from methanol. The Mo(VI) atom is coordinated by two oxide O atoms and by two O atoms and one N atom of the tridentate 1-[(2-oxidopropyl)iminomethyl]-2-naphtholate Schiff base ligand. The coordina...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979794/ https://www.ncbi.nlm.nih.gov/pubmed/21579666 http://dx.doi.org/10.1107/S160053681000262X |
Sumario: | Crystals of the title compound, [Mo(C(14)H(13)NO(2))O(2)(CH(4)O)], were obtained by recrystallization from methanol. The Mo(VI) atom is coordinated by two oxide O atoms and by two O atoms and one N atom of the tridentate 1-[(2-oxidopropyl)iminomethyl]-2-naphtholate Schiff base ligand. The coordination sphere is completed by the O atom of a methanol molecule, yielding a distorted octahedron. O—H⋯O hydrogen bonding yields centrosymmetric dimers. |
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