Methano­ldioxido{1-[(2RS)-(2-oxidoprop­yl)iminometh­yl]-2-naphtholato}molybdenium(VI)

Crystals of the title compound, [Mo(C(14)H(13)NO(2))O(2)(CH(4)O)], were obtained by recrystallization from methanol. The Mo(VI) atom is coordinated by two oxide O atoms and by two O atoms and one N atom of the tridentate 1-[(2-oxidoprop­yl)iminometh­yl]-2-naphtholate Schiff base ligand. The coordina...

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Detalles Bibliográficos
Autores principales: Niaz, Monadi, Iran, Sheikhshoaie, Abdolreza, Rezaeifard
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979794/
https://www.ncbi.nlm.nih.gov/pubmed/21579666
http://dx.doi.org/10.1107/S160053681000262X
Descripción
Sumario:Crystals of the title compound, [Mo(C(14)H(13)NO(2))O(2)(CH(4)O)], were obtained by recrystallization from methanol. The Mo(VI) atom is coordinated by two oxide O atoms and by two O atoms and one N atom of the tridentate 1-[(2-oxidoprop­yl)iminometh­yl]-2-naphtholate Schiff base ligand. The coordination sphere is completed by the O atom of a methanol mol­ecule, yielding a distorted octa­hedron. O—H⋯O hydrogen bonding yields centrosymmetric dimers.

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