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Methanoldioxido{1-[(2RS)-(2-oxidopropyl)iminomethyl]-2-naphtholato}molybdenium(VI)
Crystals of the title compound, [Mo(C(14)H(13)NO(2))O(2)(CH(4)O)], were obtained by recrystallization from methanol. The Mo(VI) atom is coordinated by two oxide O atoms and by two O atoms and one N atom of the tridentate 1-[(2-oxidopropyl)iminomethyl]-2-naphtholate Schiff base ligand. The coordina...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979794/ https://www.ncbi.nlm.nih.gov/pubmed/21579666 http://dx.doi.org/10.1107/S160053681000262X |
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author | Niaz, Monadi Iran, Sheikhshoaie Abdolreza, Rezaeifard |
author_facet | Niaz, Monadi Iran, Sheikhshoaie Abdolreza, Rezaeifard |
author_sort | Niaz, Monadi |
collection | PubMed |
description | Crystals of the title compound, [Mo(C(14)H(13)NO(2))O(2)(CH(4)O)], were obtained by recrystallization from methanol. The Mo(VI) atom is coordinated by two oxide O atoms and by two O atoms and one N atom of the tridentate 1-[(2-oxidopropyl)iminomethyl]-2-naphtholate Schiff base ligand. The coordination sphere is completed by the O atom of a methanol molecule, yielding a distorted octahedron. O—H⋯O hydrogen bonding yields centrosymmetric dimers. |
format | Text |
id | pubmed-2979794 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29797942010-12-30 Methanoldioxido{1-[(2RS)-(2-oxidopropyl)iminomethyl]-2-naphtholato}molybdenium(VI) Niaz, Monadi Iran, Sheikhshoaie Abdolreza, Rezaeifard Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Crystals of the title compound, [Mo(C(14)H(13)NO(2))O(2)(CH(4)O)], were obtained by recrystallization from methanol. The Mo(VI) atom is coordinated by two oxide O atoms and by two O atoms and one N atom of the tridentate 1-[(2-oxidopropyl)iminomethyl]-2-naphtholate Schiff base ligand. The coordination sphere is completed by the O atom of a methanol molecule, yielding a distorted octahedron. O—H⋯O hydrogen bonding yields centrosymmetric dimers. International Union of Crystallography 2010-01-27 /pmc/articles/PMC2979794/ /pubmed/21579666 http://dx.doi.org/10.1107/S160053681000262X Text en © Niaz et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Niaz, Monadi Iran, Sheikhshoaie Abdolreza, Rezaeifard Methanoldioxido{1-[(2RS)-(2-oxidopropyl)iminomethyl]-2-naphtholato}molybdenium(VI) |
title | Methanoldioxido{1-[(2RS)-(2-oxidopropyl)iminomethyl]-2-naphtholato}molybdenium(VI) |
title_full | Methanoldioxido{1-[(2RS)-(2-oxidopropyl)iminomethyl]-2-naphtholato}molybdenium(VI) |
title_fullStr | Methanoldioxido{1-[(2RS)-(2-oxidopropyl)iminomethyl]-2-naphtholato}molybdenium(VI) |
title_full_unstemmed | Methanoldioxido{1-[(2RS)-(2-oxidopropyl)iminomethyl]-2-naphtholato}molybdenium(VI) |
title_short | Methanoldioxido{1-[(2RS)-(2-oxidopropyl)iminomethyl]-2-naphtholato}molybdenium(VI) |
title_sort | methanoldioxido{1-[(2rs)-(2-oxidopropyl)iminomethyl]-2-naphtholato}molybdenium(vi) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979794/ https://www.ncbi.nlm.nih.gov/pubmed/21579666 http://dx.doi.org/10.1107/S160053681000262X |
work_keys_str_mv | AT niazmonadi methanoldioxido12rs2oxidopropyliminomethyl2naphtholatomolybdeniumvi AT iransheikhshoaie methanoldioxido12rs2oxidopropyliminomethyl2naphtholatomolybdeniumvi AT abdolrezarezaeifard methanoldioxido12rs2oxidopropyliminomethyl2naphtholatomolybdeniumvi |