Bis(N-phenyl­ethane-1,2-diamine)dithio­cyanato­nickel(II)

The asymmetric unit of the title mononuclear Ni(II) compound, [Ni(NCS)(2)(C(8)H(12)N(2))(2)], contains two independent half-mol­ecules, the Ni atoms of which lie on crystallographic inversion centres. Each Ni(II) ion is chelated by two N atoms from two N-phenyl­ethane-1,2-diamine ligands and is also...

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Detalles Bibliográficos
Autores principales: Wang, Chen-Yi, Cao, Feng, Wang, Ping, Lv, Chun-Yan, Wu, Xiang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979796/
https://www.ncbi.nlm.nih.gov/pubmed/21579606
http://dx.doi.org/10.1107/S1600536809055792
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author Wang, Chen-Yi
Cao, Feng
Wang, Ping
Lv, Chun-Yan
Wu, Xiang
author_facet Wang, Chen-Yi
Cao, Feng
Wang, Ping
Lv, Chun-Yan
Wu, Xiang
author_sort Wang, Chen-Yi
collection PubMed
description The asymmetric unit of the title mononuclear Ni(II) compound, [Ni(NCS)(2)(C(8)H(12)N(2))(2)], contains two independent half-mol­ecules, the Ni atoms of which lie on crystallographic inversion centres. Each Ni(II) ion is chelated by two N atoms from two N-phenyl­ethane-1,2-diamine ligands and is also coordinated by two N atoms from two thio­cyanate ligands, giving a distorted octa­hedral geometry. In the crystal, mol­ecules are linked into a two-dimensional network parallel to (100) by N—H⋯S inter­actions.
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spelling pubmed-29797962010-12-30 Bis(N-phenyl­ethane-1,2-diamine)dithio­cyanato­nickel(II) Wang, Chen-Yi Cao, Feng Wang, Ping Lv, Chun-Yan Wu, Xiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title mononuclear Ni(II) compound, [Ni(NCS)(2)(C(8)H(12)N(2))(2)], contains two independent half-mol­ecules, the Ni atoms of which lie on crystallographic inversion centres. Each Ni(II) ion is chelated by two N atoms from two N-phenyl­ethane-1,2-diamine ligands and is also coordinated by two N atoms from two thio­cyanate ligands, giving a distorted octa­hedral geometry. In the crystal, mol­ecules are linked into a two-dimensional network parallel to (100) by N—H⋯S inter­actions. International Union of Crystallography 2010-01-09 /pmc/articles/PMC2979796/ /pubmed/21579606 http://dx.doi.org/10.1107/S1600536809055792 Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Chen-Yi
Cao, Feng
Wang, Ping
Lv, Chun-Yan
Wu, Xiang
Bis(N-phenyl­ethane-1,2-diamine)dithio­cyanato­nickel(II)
title Bis(N-phenyl­ethane-1,2-diamine)dithio­cyanato­nickel(II)
title_full Bis(N-phenyl­ethane-1,2-diamine)dithio­cyanato­nickel(II)
title_fullStr Bis(N-phenyl­ethane-1,2-diamine)dithio­cyanato­nickel(II)
title_full_unstemmed Bis(N-phenyl­ethane-1,2-diamine)dithio­cyanato­nickel(II)
title_short Bis(N-phenyl­ethane-1,2-diamine)dithio­cyanato­nickel(II)
title_sort bis(n-phenyl­ethane-1,2-diamine)dithio­cyanato­nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979796/
https://www.ncbi.nlm.nih.gov/pubmed/21579606
http://dx.doi.org/10.1107/S1600536809055792
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AT lvchunyan bisnphenylethane12diaminedithiocyanatonickelii
AT wuxiang bisnphenylethane12diaminedithiocyanatonickelii

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