catena-Poly[[dipyridine­nickel(II)]-trans-di-μ-chlorido] from powder data

The asymetric unit of the title compound, [NiCl(2)(C(5)H(5)N)(2)](n), contains two Ni(II) ions located on different twofold rotational axes, two chloride anions and two pyridine rings in general positions. Each Ni(II) ion is coordinated by two pyridine rings, which form dihedral angles of 33.0 (2) a...

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Detalles Bibliográficos
Autores principales: Alig, Edith, Bernert, Thomas, Fink, Lothar, Külcü, Nevzat, Yeşilkaynak, Tuncay
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979813/
https://www.ncbi.nlm.nih.gov/pubmed/21579692
http://dx.doi.org/10.1107/S1600536810001820
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author Alig, Edith
Bernert, Thomas
Fink, Lothar
Külcü, Nevzat
Yeşilkaynak, Tuncay
author_facet Alig, Edith
Bernert, Thomas
Fink, Lothar
Külcü, Nevzat
Yeşilkaynak, Tuncay
author_sort Alig, Edith
collection PubMed
description The asymetric unit of the title compound, [NiCl(2)(C(5)H(5)N)(2)](n), contains two Ni(II) ions located on different twofold rotational axes, two chloride anions and two pyridine rings in general positions. Each Ni(II) ion is coordinated by two pyridine rings, which form dihedral angles of 33.0 (2) and 11.0 (2)° for the two centers, and four chloride anions in a distorted octa­hedral geometry. The chloride anions bridge Ni(II) ions related by translation along the short b axes into two crystallographically independent polymeric chains.
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spelling pubmed-29798132010-12-30 catena-Poly[[dipyridine­nickel(II)]-trans-di-μ-chlorido] from powder data Alig, Edith Bernert, Thomas Fink, Lothar Külcü, Nevzat Yeşilkaynak, Tuncay Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymetric unit of the title compound, [NiCl(2)(C(5)H(5)N)(2)](n), contains two Ni(II) ions located on different twofold rotational axes, two chloride anions and two pyridine rings in general positions. Each Ni(II) ion is coordinated by two pyridine rings, which form dihedral angles of 33.0 (2) and 11.0 (2)° for the two centers, and four chloride anions in a distorted octa­hedral geometry. The chloride anions bridge Ni(II) ions related by translation along the short b axes into two crystallographically independent polymeric chains. International Union of Crystallography 2010-01-30 /pmc/articles/PMC2979813/ /pubmed/21579692 http://dx.doi.org/10.1107/S1600536810001820 Text en © Alig et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Alig, Edith
Bernert, Thomas
Fink, Lothar
Külcü, Nevzat
Yeşilkaynak, Tuncay
catena-Poly[[dipyridine­nickel(II)]-trans-di-μ-chlorido] from powder data
title catena-Poly[[dipyridine­nickel(II)]-trans-di-μ-chlorido] from powder data
title_full catena-Poly[[dipyridine­nickel(II)]-trans-di-μ-chlorido] from powder data
title_fullStr catena-Poly[[dipyridine­nickel(II)]-trans-di-μ-chlorido] from powder data
title_full_unstemmed catena-Poly[[dipyridine­nickel(II)]-trans-di-μ-chlorido] from powder data
title_short catena-Poly[[dipyridine­nickel(II)]-trans-di-μ-chlorido] from powder data
title_sort catena-poly[[dipyridine­nickel(ii)]-trans-di-μ-chlorido] from powder data
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979813/
https://www.ncbi.nlm.nih.gov/pubmed/21579692
http://dx.doi.org/10.1107/S1600536810001820
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AT kulcunevzat catenapolydipyridinenickeliitransdimchloridofrompowderdata
AT yesilkaynaktuncay catenapolydipyridinenickeliitransdimchloridofrompowderdata

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