Tricyclo­[3.3.1.0(3,7)]nonane-3,7-diyl bis­(methane­sulfonate)

The crystal structure of the title compound, C(11)H(18)O(6)S(2), was determined to investigate the effect of the eclipsed mesyl groups on the bond length of the vicinal quaternary C atoms. The two quaternary C atoms of the noradamantane skeleton and the two O atoms to which they are connected all lo...

Descripción completa

Detalles Bibliográficos
Autores principales: Ioannou, Savvas, Nicolaides, Athanassios V., Manos, Manolis J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979816/
https://www.ncbi.nlm.nih.gov/pubmed/21579828
http://dx.doi.org/10.1107/S1600536810001261
_version_ 1782191508334575616
author Ioannou, Savvas
Nicolaides, Athanassios V.
Manos, Manolis J.
author_facet Ioannou, Savvas
Nicolaides, Athanassios V.
Manos, Manolis J.
author_sort Ioannou, Savvas
collection PubMed
description The crystal structure of the title compound, C(11)H(18)O(6)S(2), was determined to investigate the effect of the eclipsed mesyl groups on the bond length of the vicinal quaternary C atoms. The two quaternary C atoms of the noradamantane skeleton and the two O atoms to which they are connected all located essentially in the same plane [maximum deviation 0.01 Å], resulting in an eclipsing conformation of the C—O bonds. The C—C bond of the quaternary C atoms is 1.597 (3) Å is considerably longer than the other C—C bonds of the mol­ecule.
format Text
id pubmed-2979816
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29798162010-12-30 Tricyclo­[3.3.1.0(3,7)]nonane-3,7-diyl bis­(methane­sulfonate) Ioannou, Savvas Nicolaides, Athanassios V. Manos, Manolis J. Acta Crystallogr Sect E Struct Rep Online Organic Papers The crystal structure of the title compound, C(11)H(18)O(6)S(2), was determined to investigate the effect of the eclipsed mesyl groups on the bond length of the vicinal quaternary C atoms. The two quaternary C atoms of the noradamantane skeleton and the two O atoms to which they are connected all located essentially in the same plane [maximum deviation 0.01 Å], resulting in an eclipsing conformation of the C—O bonds. The C—C bond of the quaternary C atoms is 1.597 (3) Å is considerably longer than the other C—C bonds of the mol­ecule. International Union of Crystallography 2010-01-20 /pmc/articles/PMC2979816/ /pubmed/21579828 http://dx.doi.org/10.1107/S1600536810001261 Text en © Ioannou et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ioannou, Savvas
Nicolaides, Athanassios V.
Manos, Manolis J.
Tricyclo­[3.3.1.0(3,7)]nonane-3,7-diyl bis­(methane­sulfonate)
title Tricyclo­[3.3.1.0(3,7)]nonane-3,7-diyl bis­(methane­sulfonate)
title_full Tricyclo­[3.3.1.0(3,7)]nonane-3,7-diyl bis­(methane­sulfonate)
title_fullStr Tricyclo­[3.3.1.0(3,7)]nonane-3,7-diyl bis­(methane­sulfonate)
title_full_unstemmed Tricyclo­[3.3.1.0(3,7)]nonane-3,7-diyl bis­(methane­sulfonate)
title_short Tricyclo­[3.3.1.0(3,7)]nonane-3,7-diyl bis­(methane­sulfonate)
title_sort tricyclo­[3.3.1.0(3,7)]nonane-3,7-diyl bis­(methane­sulfonate)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979816/
https://www.ncbi.nlm.nih.gov/pubmed/21579828
http://dx.doi.org/10.1107/S1600536810001261
work_keys_str_mv AT ioannousavvas tricyclo331037nonane37diylbismethanesulfonate
AT nicolaidesathanassiosv tricyclo331037nonane37diylbismethanesulfonate
AT manosmanolisj tricyclo331037nonane37diylbismethanesulfonate

Ejemplares similares