catena-Poly[[[aqua­(5-nitro­benzene-1,2,3-tricarboxyl­ato-κO (1))copper(II)]-di-μ-aqua-[diaqua­sodium]-di-μ-aqua] tetra­hydrate]

In the heteronuclear coordination polymer, {[CuNa(C(9)H(2)NO(8))(H(2)O)(7)]·4H(2)O}(n), the Cu(II) atom is coordinated by six O atoms from five water mol­ecules and one 5-nitro­benzene-1,2,3-tricarboxyl­ate ligand in a slightly distorted octa­hedral geometry. The Na(+) cation is surrounded by six wa...

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Detalles Bibliográficos
Autores principales: Ding, Yong-Jie, Zhao, Chun-Xiang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979819/
https://www.ncbi.nlm.nih.gov/pubmed/21579616
http://dx.doi.org/10.1107/S1600536810000401
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author Ding, Yong-Jie
Zhao, Chun-Xiang
author_facet Ding, Yong-Jie
Zhao, Chun-Xiang
author_sort Ding, Yong-Jie
collection PubMed
description In the heteronuclear coordination polymer, {[CuNa(C(9)H(2)NO(8))(H(2)O)(7)]·4H(2)O}(n), the Cu(II) atom is coordinated by six O atoms from five water mol­ecules and one 5-nitro­benzene-1,2,3-tricarboxyl­ate ligand in a slightly distorted octa­hedral geometry. The Na(+) cation is surrounded by six water mol­ecules in an irregular trigonal-prismatic geometry. The Cu and Na atoms are connected by water bridges, forming an infinite chain. O—H⋯O hydrogen bonds involving the coordinated and uncoordinated water mol­ecules connect the chains into a three-dimensional network.
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spelling pubmed-29798192010-12-30 catena-Poly[[[aqua­(5-nitro­benzene-1,2,3-tricarboxyl­ato-κO (1))copper(II)]-di-μ-aqua-[diaqua­sodium]-di-μ-aqua] tetra­hydrate] Ding, Yong-Jie Zhao, Chun-Xiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the heteronuclear coordination polymer, {[CuNa(C(9)H(2)NO(8))(H(2)O)(7)]·4H(2)O}(n), the Cu(II) atom is coordinated by six O atoms from five water mol­ecules and one 5-nitro­benzene-1,2,3-tricarboxyl­ate ligand in a slightly distorted octa­hedral geometry. The Na(+) cation is surrounded by six water mol­ecules in an irregular trigonal-prismatic geometry. The Cu and Na atoms are connected by water bridges, forming an infinite chain. O—H⋯O hydrogen bonds involving the coordinated and uncoordinated water mol­ecules connect the chains into a three-dimensional network. International Union of Crystallography 2010-01-09 /pmc/articles/PMC2979819/ /pubmed/21579616 http://dx.doi.org/10.1107/S1600536810000401 Text en © Ding and Zhao 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ding, Yong-Jie
Zhao, Chun-Xiang
catena-Poly[[[aqua­(5-nitro­benzene-1,2,3-tricarboxyl­ato-κO (1))copper(II)]-di-μ-aqua-[diaqua­sodium]-di-μ-aqua] tetra­hydrate]
title catena-Poly[[[aqua­(5-nitro­benzene-1,2,3-tricarboxyl­ato-κO (1))copper(II)]-di-μ-aqua-[diaqua­sodium]-di-μ-aqua] tetra­hydrate]
title_full catena-Poly[[[aqua­(5-nitro­benzene-1,2,3-tricarboxyl­ato-κO (1))copper(II)]-di-μ-aqua-[diaqua­sodium]-di-μ-aqua] tetra­hydrate]
title_fullStr catena-Poly[[[aqua­(5-nitro­benzene-1,2,3-tricarboxyl­ato-κO (1))copper(II)]-di-μ-aqua-[diaqua­sodium]-di-μ-aqua] tetra­hydrate]
title_full_unstemmed catena-Poly[[[aqua­(5-nitro­benzene-1,2,3-tricarboxyl­ato-κO (1))copper(II)]-di-μ-aqua-[diaqua­sodium]-di-μ-aqua] tetra­hydrate]
title_short catena-Poly[[[aqua­(5-nitro­benzene-1,2,3-tricarboxyl­ato-κO (1))copper(II)]-di-μ-aqua-[diaqua­sodium]-di-μ-aqua] tetra­hydrate]
title_sort catena-poly[[[aqua­(5-nitro­benzene-1,2,3-tricarboxyl­ato-κo (1))copper(ii)]-di-μ-aqua-[diaqua­sodium]-di-μ-aqua] tetra­hydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979819/
https://www.ncbi.nlm.nih.gov/pubmed/21579616
http://dx.doi.org/10.1107/S1600536810000401
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AT zhaochunxiang catenapolyaqua5nitrobenzene123tricarboxylatoko1copperiidimaquadiaquasodiumdimaquatetrahydrate

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