catena-Poly[[(4-amino­benzoato)aqua­silver(I)]-μ-hexa­methyl­enetetramine]

In the title coordination polymer, [Ag(C(7)H(6)NO(2))(C(6)H(12)N(4))(H(2)O)](n), the Ag(I) ion is five-coordinated by two carboxyl­ate O atoms from one 4-amino­benzoate anion (L), two N atoms from two different hexa­methyl­enetetramine (hmt) ligands, and one water O atom in a distorted square-pyrami...

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Detalles Bibliográficos
Autores principales: Han, Jia-Jun, Zhang, Tian-Yun, Geng, Lin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979826/
https://www.ncbi.nlm.nih.gov/pubmed/21579600
http://dx.doi.org/10.1107/S1600536809055044
Descripción
Sumario:In the title coordination polymer, [Ag(C(7)H(6)NO(2))(C(6)H(12)N(4))(H(2)O)](n), the Ag(I) ion is five-coordinated by two carboxyl­ate O atoms from one 4-amino­benzoate anion (L), two N atoms from two different hexa­methyl­enetetramine (hmt) ligands, and one water O atom in a distorted square-pyramidal geometry. The metal atom lies on a mirror plane and the L anion, hmt ligand and water mol­ecule all lie across crystallographic mirror planes. Each hmt ligand bridges two neighboring Ag(I) ions, resulting in the formation of a chain structure along the b axis. The chains are linked into a three-dimensional framework by N—H⋯O and O—H⋯O hydrogen bonds.

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