catena-Poly[[(4-amino­benzoato)aqua­silver(I)]-μ-hexa­methyl­enetetramine]

In the title coordination polymer, [Ag(C(7)H(6)NO(2))(C(6)H(12)N(4))(H(2)O)](n), the Ag(I) ion is five-coordinated by two carboxyl­ate O atoms from one 4-amino­benzoate anion (L), two N atoms from two different hexa­methyl­enetetramine (hmt) ligands, and one water O atom in a distorted square-pyrami...

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Detalles Bibliográficos
Autores principales: Han, Jia-Jun, Zhang, Tian-Yun, Geng, Lin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979826/
https://www.ncbi.nlm.nih.gov/pubmed/21579600
http://dx.doi.org/10.1107/S1600536809055044
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author Han, Jia-Jun
Zhang, Tian-Yun
Geng, Lin
author_facet Han, Jia-Jun
Zhang, Tian-Yun
Geng, Lin
author_sort Han, Jia-Jun
collection PubMed
description In the title coordination polymer, [Ag(C(7)H(6)NO(2))(C(6)H(12)N(4))(H(2)O)](n), the Ag(I) ion is five-coordinated by two carboxyl­ate O atoms from one 4-amino­benzoate anion (L), two N atoms from two different hexa­methyl­enetetramine (hmt) ligands, and one water O atom in a distorted square-pyramidal geometry. The metal atom lies on a mirror plane and the L anion, hmt ligand and water mol­ecule all lie across crystallographic mirror planes. Each hmt ligand bridges two neighboring Ag(I) ions, resulting in the formation of a chain structure along the b axis. The chains are linked into a three-dimensional framework by N—H⋯O and O—H⋯O hydrogen bonds.
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spelling pubmed-29798262010-12-30 catena-Poly[[(4-amino­benzoato)aqua­silver(I)]-μ-hexa­methyl­enetetramine] Han, Jia-Jun Zhang, Tian-Yun Geng, Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [Ag(C(7)H(6)NO(2))(C(6)H(12)N(4))(H(2)O)](n), the Ag(I) ion is five-coordinated by two carboxyl­ate O atoms from one 4-amino­benzoate anion (L), two N atoms from two different hexa­methyl­enetetramine (hmt) ligands, and one water O atom in a distorted square-pyramidal geometry. The metal atom lies on a mirror plane and the L anion, hmt ligand and water mol­ecule all lie across crystallographic mirror planes. Each hmt ligand bridges two neighboring Ag(I) ions, resulting in the formation of a chain structure along the b axis. The chains are linked into a three-dimensional framework by N—H⋯O and O—H⋯O hydrogen bonds. International Union of Crystallography 2010-01-09 /pmc/articles/PMC2979826/ /pubmed/21579600 http://dx.doi.org/10.1107/S1600536809055044 Text en © Han et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Han, Jia-Jun
Zhang, Tian-Yun
Geng, Lin
catena-Poly[[(4-amino­benzoato)aqua­silver(I)]-μ-hexa­methyl­enetetramine]
title catena-Poly[[(4-amino­benzoato)aqua­silver(I)]-μ-hexa­methyl­enetetramine]
title_full catena-Poly[[(4-amino­benzoato)aqua­silver(I)]-μ-hexa­methyl­enetetramine]
title_fullStr catena-Poly[[(4-amino­benzoato)aqua­silver(I)]-μ-hexa­methyl­enetetramine]
title_full_unstemmed catena-Poly[[(4-amino­benzoato)aqua­silver(I)]-μ-hexa­methyl­enetetramine]
title_short catena-Poly[[(4-amino­benzoato)aqua­silver(I)]-μ-hexa­methyl­enetetramine]
title_sort catena-poly[[(4-amino­benzoato)aqua­silver(i)]-μ-hexa­methyl­enetetramine]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979826/
https://www.ncbi.nlm.nih.gov/pubmed/21579600
http://dx.doi.org/10.1107/S1600536809055044
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