2,4-Dichloro-6-(8-quinolylamino­methyl­ene)cyclo­hexa-2,4-dien-1-one methanol solvate

The main mol­ecule of the title methanol solvate, C(16)H(10)Cl(2)N(2)O·CH(3)OH, exists in the keto form and the C=O and N—H bonds are mutually cis in the crystal structure. The dihedral angle between the quinoline and benzene rings is 11.17 (3)°. A bifurcated intra­molecular N—H⋯(O,N) hydrogen bond...

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Detalles Bibliográficos
Autores principales: Shibahara, Takashi, Takahashi, Masayuki, Maekawa, Atsushi, Takagi, Hideaki
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979828/
https://www.ncbi.nlm.nih.gov/pubmed/21579844
http://dx.doi.org/10.1107/S1600536810002345
Descripción
Sumario:The main mol­ecule of the title methanol solvate, C(16)H(10)Cl(2)N(2)O·CH(3)OH, exists in the keto form and the C=O and N—H bonds are mutually cis in the crystal structure. The dihedral angle between the quinoline and benzene rings is 11.17 (3)°. A bifurcated intra­molecular N—H⋯(O,N) hydrogen bond is present as well as an O—H⋯O hydrogen bond. In the crystal, C—H⋯O inter­actions link the 3,5-dichloro­salicyl­idene-8-amino­quinoline and methanol mol­ecules.

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