2,4-Dichloro-6-(8-quinolylamino­methyl­ene)cyclo­hexa-2,4-dien-1-one methanol solvate

The main mol­ecule of the title methanol solvate, C(16)H(10)Cl(2)N(2)O·CH(3)OH, exists in the keto form and the C=O and N—H bonds are mutually cis in the crystal structure. The dihedral angle between the quinoline and benzene rings is 11.17 (3)°. A bifurcated intra­molecular N—H⋯(O,N) hydrogen bond...

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Detalles Bibliográficos
Autores principales: Shibahara, Takashi, Takahashi, Masayuki, Maekawa, Atsushi, Takagi, Hideaki
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979828/
https://www.ncbi.nlm.nih.gov/pubmed/21579844
http://dx.doi.org/10.1107/S1600536810002345
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author Shibahara, Takashi
Takahashi, Masayuki
Maekawa, Atsushi
Takagi, Hideaki
author_facet Shibahara, Takashi
Takahashi, Masayuki
Maekawa, Atsushi
Takagi, Hideaki
author_sort Shibahara, Takashi
collection PubMed
description The main mol­ecule of the title methanol solvate, C(16)H(10)Cl(2)N(2)O·CH(3)OH, exists in the keto form and the C=O and N—H bonds are mutually cis in the crystal structure. The dihedral angle between the quinoline and benzene rings is 11.17 (3)°. A bifurcated intra­molecular N—H⋯(O,N) hydrogen bond is present as well as an O—H⋯O hydrogen bond. In the crystal, C—H⋯O inter­actions link the 3,5-dichloro­salicyl­idene-8-amino­quinoline and methanol mol­ecules.
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spelling pubmed-29798282010-12-30 2,4-Dichloro-6-(8-quinolylamino­methyl­ene)cyclo­hexa-2,4-dien-1-one methanol solvate Shibahara, Takashi Takahashi, Masayuki Maekawa, Atsushi Takagi, Hideaki Acta Crystallogr Sect E Struct Rep Online Organic Papers The main mol­ecule of the title methanol solvate, C(16)H(10)Cl(2)N(2)O·CH(3)OH, exists in the keto form and the C=O and N—H bonds are mutually cis in the crystal structure. The dihedral angle between the quinoline and benzene rings is 11.17 (3)°. A bifurcated intra­molecular N—H⋯(O,N) hydrogen bond is present as well as an O—H⋯O hydrogen bond. In the crystal, C—H⋯O inter­actions link the 3,5-dichloro­salicyl­idene-8-amino­quinoline and methanol mol­ecules. International Union of Crystallography 2010-01-23 /pmc/articles/PMC2979828/ /pubmed/21579844 http://dx.doi.org/10.1107/S1600536810002345 Text en © Shibahara et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shibahara, Takashi
Takahashi, Masayuki
Maekawa, Atsushi
Takagi, Hideaki
2,4-Dichloro-6-(8-quinolylamino­methyl­ene)cyclo­hexa-2,4-dien-1-one methanol solvate
title 2,4-Dichloro-6-(8-quinolylamino­methyl­ene)cyclo­hexa-2,4-dien-1-one methanol solvate
title_full 2,4-Dichloro-6-(8-quinolylamino­methyl­ene)cyclo­hexa-2,4-dien-1-one methanol solvate
title_fullStr 2,4-Dichloro-6-(8-quinolylamino­methyl­ene)cyclo­hexa-2,4-dien-1-one methanol solvate
title_full_unstemmed 2,4-Dichloro-6-(8-quinolylamino­methyl­ene)cyclo­hexa-2,4-dien-1-one methanol solvate
title_short 2,4-Dichloro-6-(8-quinolylamino­methyl­ene)cyclo­hexa-2,4-dien-1-one methanol solvate
title_sort 2,4-dichloro-6-(8-quinolylamino­methyl­ene)cyclo­hexa-2,4-dien-1-one methanol solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979828/
https://www.ncbi.nlm.nih.gov/pubmed/21579844
http://dx.doi.org/10.1107/S1600536810002345
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AT takahashimasayuki 24dichloro68quinolylaminomethylenecyclohexa24dien1onemethanolsolvate
AT maekawaatsushi 24dichloro68quinolylaminomethylenecyclohexa24dien1onemethanolsolvate
AT takagihideaki 24dichloro68quinolylaminomethylenecyclohexa24dien1onemethanolsolvate

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