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Dimethylammonium diaqua(pyridine-2,4-dicarboxylato-κ(2) N,O (2))cuprate(II)
The asymmetric unit of the title compound, (C(2)H(8)N)(2)[Cu(C(7)H(3)NO(4))(2)(H(2)O)(2)], contains one-half of a mononuclear [Cu(C(7)H(3)NO(4))(2)(H(2)O)(2)](2−) anion, one dimethylammonium cation and one aqua ligand. The Cu(II) atom, lying on an inversion center, is coordinated by two symmetry-re...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979830/ https://www.ncbi.nlm.nih.gov/pubmed/21579670 http://dx.doi.org/10.1107/S1600536810002497 |
Sumario: | The asymmetric unit of the title compound, (C(2)H(8)N)(2)[Cu(C(7)H(3)NO(4))(2)(H(2)O)(2)], contains one-half of a mononuclear [Cu(C(7)H(3)NO(4))(2)(H(2)O)(2)](2−) anion, one dimethylammonium cation and one aqua ligand. The Cu(II) atom, lying on an inversion center, is coordinated by two symmetry-related N atoms and two O atoms from one pyridine-2,4-dicarboxylate ligand and two symmetry-related aqua ligands and exhibits a distorted octahedral trans-[CuN(2)O(4)] coordination geometry. Multiple crystallographically independent O—H⋯O and N—H⋯O hydrogen bonds form a three-dimensional network in the crystal structure. |
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