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Dimethyl­ammonium diaqua­(pyridine-2,4-dicarboxyl­ato-κ(2) N,O (2))cuprate(II)

The asymmetric unit of the title compound, (C(2)H(8)N)(2)[Cu(C(7)H(3)NO(4))(2)(H(2)O)(2)], contains one-half of a mononuclear [Cu(C(7)H(3)NO(4))(2)(H(2)O)(2)](2−) anion, one dimethyl­ammonium cation and one aqua ligand. The Cu(II) atom, lying on an inversion center, is coordinated by two symmetry-re...

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Detalles Bibliográficos
Autores principales: Wang, Ji-Dong, Han, Shu-Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979830/
https://www.ncbi.nlm.nih.gov/pubmed/21579670
http://dx.doi.org/10.1107/S1600536810002497
Descripción
Sumario:The asymmetric unit of the title compound, (C(2)H(8)N)(2)[Cu(C(7)H(3)NO(4))(2)(H(2)O)(2)], contains one-half of a mononuclear [Cu(C(7)H(3)NO(4))(2)(H(2)O)(2)](2−) anion, one dimethyl­ammonium cation and one aqua ligand. The Cu(II) atom, lying on an inversion center, is coordinated by two symmetry-related N atoms and two O atoms from one pyridine-2,4-dicarboxyl­ate ligand and two symmetry-related aqua ligands and exhibits a distorted octa­hedral trans-[CuN(2)O(4)] coordination geometry. Multiple crystallographically independent O—H⋯O and N—H⋯O hydrogen bonds form a three-dimensional network in the crystal structure.