Dimethyl­ammonium diaqua­(pyridine-2,4-dicarboxyl­ato-κ(2) N,O (2))cuprate(II)

The asymmetric unit of the title compound, (C(2)H(8)N)(2)[Cu(C(7)H(3)NO(4))(2)(H(2)O)(2)], contains one-half of a mononuclear [Cu(C(7)H(3)NO(4))(2)(H(2)O)(2)](2−) anion, one dimethyl­ammonium cation and one aqua ligand. The Cu(II) atom, lying on an inversion center, is coordinated by two symmetry-re...

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Detalles Bibliográficos
Autores principales: Wang, Ji-Dong, Han, Shu-Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979830/
https://www.ncbi.nlm.nih.gov/pubmed/21579670
http://dx.doi.org/10.1107/S1600536810002497
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author Wang, Ji-Dong
Han, Shu-Min
author_facet Wang, Ji-Dong
Han, Shu-Min
author_sort Wang, Ji-Dong
collection PubMed
description The asymmetric unit of the title compound, (C(2)H(8)N)(2)[Cu(C(7)H(3)NO(4))(2)(H(2)O)(2)], contains one-half of a mononuclear [Cu(C(7)H(3)NO(4))(2)(H(2)O)(2)](2−) anion, one dimethyl­ammonium cation and one aqua ligand. The Cu(II) atom, lying on an inversion center, is coordinated by two symmetry-related N atoms and two O atoms from one pyridine-2,4-dicarboxyl­ate ligand and two symmetry-related aqua ligands and exhibits a distorted octa­hedral trans-[CuN(2)O(4)] coordination geometry. Multiple crystallographically independent O—H⋯O and N—H⋯O hydrogen bonds form a three-dimensional network in the crystal structure.
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spelling pubmed-29798302010-12-30 Dimethyl­ammonium diaqua­(pyridine-2,4-dicarboxyl­ato-κ(2) N,O (2))cuprate(II) Wang, Ji-Dong Han, Shu-Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(2)H(8)N)(2)[Cu(C(7)H(3)NO(4))(2)(H(2)O)(2)], contains one-half of a mononuclear [Cu(C(7)H(3)NO(4))(2)(H(2)O)(2)](2−) anion, one dimethyl­ammonium cation and one aqua ligand. The Cu(II) atom, lying on an inversion center, is coordinated by two symmetry-related N atoms and two O atoms from one pyridine-2,4-dicarboxyl­ate ligand and two symmetry-related aqua ligands and exhibits a distorted octa­hedral trans-[CuN(2)O(4)] coordination geometry. Multiple crystallographically independent O—H⋯O and N—H⋯O hydrogen bonds form a three-dimensional network in the crystal structure. International Union of Crystallography 2010-01-27 /pmc/articles/PMC2979830/ /pubmed/21579670 http://dx.doi.org/10.1107/S1600536810002497 Text en © Wang and Han 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Ji-Dong
Han, Shu-Min
Dimethyl­ammonium diaqua­(pyridine-2,4-dicarboxyl­ato-κ(2) N,O (2))cuprate(II)
title Dimethyl­ammonium diaqua­(pyridine-2,4-dicarboxyl­ato-κ(2) N,O (2))cuprate(II)
title_full Dimethyl­ammonium diaqua­(pyridine-2,4-dicarboxyl­ato-κ(2) N,O (2))cuprate(II)
title_fullStr Dimethyl­ammonium diaqua­(pyridine-2,4-dicarboxyl­ato-κ(2) N,O (2))cuprate(II)
title_full_unstemmed Dimethyl­ammonium diaqua­(pyridine-2,4-dicarboxyl­ato-κ(2) N,O (2))cuprate(II)
title_short Dimethyl­ammonium diaqua­(pyridine-2,4-dicarboxyl­ato-κ(2) N,O (2))cuprate(II)
title_sort dimethyl­ammonium diaqua­(pyridine-2,4-dicarboxyl­ato-κ(2) n,o (2))cuprate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979830/
https://www.ncbi.nlm.nih.gov/pubmed/21579670
http://dx.doi.org/10.1107/S1600536810002497
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AT hanshumin dimethylammoniumdiaquapyridine24dicarboxylatok2no2cuprateii

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