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(4-Amino-3-methyl­benzene­sulfonato)tri-μ-aqua-penta­aqua­disodium 4-amino-3-methyl­benzene­sulfonate

In the title compound, [Na(2)(C(7)H(8)NO(3)S)(H(2)O)(8)](C(7)H(8)NO(3)S), one Na(+) ion is bonded to six water mol­ecules in a distorted octa­hedral arrangement while the other is bonded to five water mol­ecules and one O atom of a 4-amino-3-methyl­benzene­sulfonate anion, also yielding a distorted...

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Detalles Bibliográficos
Autores principales: Tai, Xi-Shi, Zhang, Fu-Gong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979835/
https://www.ncbi.nlm.nih.gov/pubmed/21579611
http://dx.doi.org/10.1107/S1600536809055512
Descripción
Sumario:In the title compound, [Na(2)(C(7)H(8)NO(3)S)(H(2)O)(8)](C(7)H(8)NO(3)S), one Na(+) ion is bonded to six water mol­ecules in a distorted octa­hedral arrangement while the other is bonded to five water mol­ecules and one O atom of a 4-amino-3-methyl­benzene­sulfonate anion, also yielding a distorted NaO(6) octa­hedron. Three of the water molecules bridge the metal ions and an intra­molecular O—H⋯O hydrogen bond helps to establish the conformation. In the crystal, the component species inter­act by way of O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds.