Cargando…
(4-Amino-3-methylbenzenesulfonato)tri-μ-aqua-pentaaquadisodium 4-amino-3-methylbenzenesulfonate
In the title compound, [Na(2)(C(7)H(8)NO(3)S)(H(2)O)(8)](C(7)H(8)NO(3)S), one Na(+) ion is bonded to six water molecules in a distorted octahedral arrangement while the other is bonded to five water molecules and one O atom of a 4-amino-3-methylbenzenesulfonate anion, also yielding a distorted...
Autores principales: | , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979835/ https://www.ncbi.nlm.nih.gov/pubmed/21579611 http://dx.doi.org/10.1107/S1600536809055512 |
_version_ | 1782191513059459072 |
---|---|
author | Tai, Xi-Shi Zhang, Fu-Gong |
author_facet | Tai, Xi-Shi Zhang, Fu-Gong |
author_sort | Tai, Xi-Shi |
collection | PubMed |
description | In the title compound, [Na(2)(C(7)H(8)NO(3)S)(H(2)O)(8)](C(7)H(8)NO(3)S), one Na(+) ion is bonded to six water molecules in a distorted octahedral arrangement while the other is bonded to five water molecules and one O atom of a 4-amino-3-methylbenzenesulfonate anion, also yielding a distorted NaO(6) octahedron. Three of the water molecules bridge the metal ions and an intramolecular O—H⋯O hydrogen bond helps to establish the conformation. In the crystal, the component species interact by way of O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds. |
format | Text |
id | pubmed-2979835 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29798352010-12-30 (4-Amino-3-methylbenzenesulfonato)tri-μ-aqua-pentaaquadisodium 4-amino-3-methylbenzenesulfonate Tai, Xi-Shi Zhang, Fu-Gong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Na(2)(C(7)H(8)NO(3)S)(H(2)O)(8)](C(7)H(8)NO(3)S), one Na(+) ion is bonded to six water molecules in a distorted octahedral arrangement while the other is bonded to five water molecules and one O atom of a 4-amino-3-methylbenzenesulfonate anion, also yielding a distorted NaO(6) octahedron. Three of the water molecules bridge the metal ions and an intramolecular O—H⋯O hydrogen bond helps to establish the conformation. In the crystal, the component species interact by way of O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds. International Union of Crystallography 2010-01-09 /pmc/articles/PMC2979835/ /pubmed/21579611 http://dx.doi.org/10.1107/S1600536809055512 Text en © Tai and Zhang 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Tai, Xi-Shi Zhang, Fu-Gong (4-Amino-3-methylbenzenesulfonato)tri-μ-aqua-pentaaquadisodium 4-amino-3-methylbenzenesulfonate |
title | (4-Amino-3-methylbenzenesulfonato)tri-μ-aqua-pentaaquadisodium 4-amino-3-methylbenzenesulfonate |
title_full | (4-Amino-3-methylbenzenesulfonato)tri-μ-aqua-pentaaquadisodium 4-amino-3-methylbenzenesulfonate |
title_fullStr | (4-Amino-3-methylbenzenesulfonato)tri-μ-aqua-pentaaquadisodium 4-amino-3-methylbenzenesulfonate |
title_full_unstemmed | (4-Amino-3-methylbenzenesulfonato)tri-μ-aqua-pentaaquadisodium 4-amino-3-methylbenzenesulfonate |
title_short | (4-Amino-3-methylbenzenesulfonato)tri-μ-aqua-pentaaquadisodium 4-amino-3-methylbenzenesulfonate |
title_sort | (4-amino-3-methylbenzenesulfonato)tri-μ-aqua-pentaaquadisodium 4-amino-3-methylbenzenesulfonate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979835/ https://www.ncbi.nlm.nih.gov/pubmed/21579611 http://dx.doi.org/10.1107/S1600536809055512 |
work_keys_str_mv | AT taixishi 4amino3methylbenzenesulfonatotrimaquapentaaquadisodium4amino3methylbenzenesulfonate AT zhangfugong 4amino3methylbenzenesulfonatotrimaquapentaaquadisodium4amino3methylbenzenesulfonate |