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Octaaquabis(μ(2)-1H-pyrazole-3,5-dicarboxylato)tricopper(II) tetrahydrate
In the trinucler Cu(II) complex molecule of the title compound, [Cu(3)(C(5)HN(2)O(4))(2)(H(2)O)(8)]·4H(2)O, the central Cu(II) atom is located on an inversion centre and is coordinated in a distorted octahedral geometry. The equatorial sites are occupied by two N and two O atoms from two pyrazole-...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979837/ https://www.ncbi.nlm.nih.gov/pubmed/21579677 http://dx.doi.org/10.1107/S1600536810001595 |
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author | Li, Zhi-Gang Li, Shao-Ai Liu, De-Quan Huang, Yi-Hua Xu, Jing-Wei |
author_facet | Li, Zhi-Gang Li, Shao-Ai Liu, De-Quan Huang, Yi-Hua Xu, Jing-Wei |
author_sort | Li, Zhi-Gang |
collection | PubMed |
description | In the trinucler Cu(II) complex molecule of the title compound, [Cu(3)(C(5)HN(2)O(4))(2)(H(2)O)(8)]·4H(2)O, the central Cu(II) atom is located on an inversion centre and is coordinated in a distorted octahedral geometry. The equatorial sites are occupied by two N and two O atoms from two pyrazole-3,5-dicarboxylate ligands and the axial positions are occupied by two water molecules. The two other symmetry-related Cu(II) atoms are pentacoordinated and assume a square-pyramidal geometry. In the crystal structure, coordinated and uncoordinated water molecules and carboxylate O atoms are linked by O—H⋯O hydrogen bonds. |
format | Text |
id | pubmed-2979837 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29798372010-12-30 Octaaquabis(μ(2)-1H-pyrazole-3,5-dicarboxylato)tricopper(II) tetrahydrate Li, Zhi-Gang Li, Shao-Ai Liu, De-Quan Huang, Yi-Hua Xu, Jing-Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the trinucler Cu(II) complex molecule of the title compound, [Cu(3)(C(5)HN(2)O(4))(2)(H(2)O)(8)]·4H(2)O, the central Cu(II) atom is located on an inversion centre and is coordinated in a distorted octahedral geometry. The equatorial sites are occupied by two N and two O atoms from two pyrazole-3,5-dicarboxylate ligands and the axial positions are occupied by two water molecules. The two other symmetry-related Cu(II) atoms are pentacoordinated and assume a square-pyramidal geometry. In the crystal structure, coordinated and uncoordinated water molecules and carboxylate O atoms are linked by O—H⋯O hydrogen bonds. International Union of Crystallography 2010-01-30 /pmc/articles/PMC2979837/ /pubmed/21579677 http://dx.doi.org/10.1107/S1600536810001595 Text en © Li et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Li, Zhi-Gang Li, Shao-Ai Liu, De-Quan Huang, Yi-Hua Xu, Jing-Wei Octaaquabis(μ(2)-1H-pyrazole-3,5-dicarboxylato)tricopper(II) tetrahydrate |
title | Octaaquabis(μ(2)-1H-pyrazole-3,5-dicarboxylato)tricopper(II) tetrahydrate |
title_full | Octaaquabis(μ(2)-1H-pyrazole-3,5-dicarboxylato)tricopper(II) tetrahydrate |
title_fullStr | Octaaquabis(μ(2)-1H-pyrazole-3,5-dicarboxylato)tricopper(II) tetrahydrate |
title_full_unstemmed | Octaaquabis(μ(2)-1H-pyrazole-3,5-dicarboxylato)tricopper(II) tetrahydrate |
title_short | Octaaquabis(μ(2)-1H-pyrazole-3,5-dicarboxylato)tricopper(II) tetrahydrate |
title_sort | octaaquabis(μ(2)-1h-pyrazole-3,5-dicarboxylato)tricopper(ii) tetrahydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979837/ https://www.ncbi.nlm.nih.gov/pubmed/21579677 http://dx.doi.org/10.1107/S1600536810001595 |
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