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catena-Poly[[aquasodium(I)]-μ-[2,2′-(disulfanediyl)bis(pyridine N-oxide)]-μ-(pyridine-2-thiolato 1-oxide)]
There are two monomeric units in the asymmetric unit of the polymeric title compound, [Na(C(5)H(4)NOS)(C(10)H(8)N(2)O(2)S(2))(H(2)O)](n). The Na(I) ions are six coordinated by four O atoms, one S atom and one water molecule, forming a slightly distorted octahedral geometry. An intramolecular O—H⋯...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979839/ https://www.ncbi.nlm.nih.gov/pubmed/21579623 http://dx.doi.org/10.1107/S1600536810000073 |
Sumario: | There are two monomeric units in the asymmetric unit of the polymeric title compound, [Na(C(5)H(4)NOS)(C(10)H(8)N(2)O(2)S(2))(H(2)O)](n). The Na(I) ions are six coordinated by four O atoms, one S atom and one water molecule, forming a slightly distorted octahedral geometry. An intramolecular O—H⋯O hydrogen bond stabilizes the conformation of the molecule. The crystal packing is consolidated by intermolecular O—H⋯O, O—H⋯N and O—H⋯S hydrogen bonds, π–π interactions [with centroid–centroid distances of 3.587 (2) Å] together with weak C—H⋯π interactions. The molecules are linked into polymeric chains along the b-axis direction. |
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