O,O′-Di-p-tolyl­pyrophospho­ric bis­(dimethyl­amide)

The title compound, C(18)H(26)N(2)O(5)P(2), was obtained accidently from the reaction between N,N-dimethyl­phospho­ramido­chloridic acid 4-methyl phenyl ester, NaNO(2) and 18-crown-6 in acetonitrile under reflux conditions. The asymmetric unit contains one half-mol­ecule, the complete mol­ecule bein...

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Detalles Bibliográficos
Autores principales: Pourayoubi, Mehrdad, Ghadimi, Saied, Ebrahimi Valmoozi, Ali Asghar
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979840/
https://www.ncbi.nlm.nih.gov/pubmed/21579865
http://dx.doi.org/10.1107/S1600536810002692
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author Pourayoubi, Mehrdad
Ghadimi, Saied
Ebrahimi Valmoozi, Ali Asghar
author_facet Pourayoubi, Mehrdad
Ghadimi, Saied
Ebrahimi Valmoozi, Ali Asghar
author_sort Pourayoubi, Mehrdad
collection PubMed
description The title compound, C(18)H(26)N(2)O(5)P(2), was obtained accidently from the reaction between N,N-dimethyl­phospho­ramido­chloridic acid 4-methyl phenyl ester, NaNO(2) and 18-crown-6 in acetonitrile under reflux conditions. The asymmetric unit contains one half-mol­ecule, the complete mol­ecule being generated by crystallographic twofold symmetry, with the bridging O atom lying on the rotation axis. The P atoms exhibit a tetra­hedral coordination and are bridged via one O atom [P—O—P angle = 130.00 (19)°].
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spelling pubmed-29798402010-12-30 O,O′-Di-p-tolyl­pyrophospho­ric bis­(dimethyl­amide) Pourayoubi, Mehrdad Ghadimi, Saied Ebrahimi Valmoozi, Ali Asghar Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(18)H(26)N(2)O(5)P(2), was obtained accidently from the reaction between N,N-dimethyl­phospho­ramido­chloridic acid 4-methyl phenyl ester, NaNO(2) and 18-crown-6 in acetonitrile under reflux conditions. The asymmetric unit contains one half-mol­ecule, the complete mol­ecule being generated by crystallographic twofold symmetry, with the bridging O atom lying on the rotation axis. The P atoms exhibit a tetra­hedral coordination and are bridged via one O atom [P—O—P angle = 130.00 (19)°]. International Union of Crystallography 2010-01-27 /pmc/articles/PMC2979840/ /pubmed/21579865 http://dx.doi.org/10.1107/S1600536810002692 Text en © Pourayoubi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Pourayoubi, Mehrdad
Ghadimi, Saied
Ebrahimi Valmoozi, Ali Asghar
O,O′-Di-p-tolyl­pyrophospho­ric bis­(dimethyl­amide)
title O,O′-Di-p-tolyl­pyrophospho­ric bis­(dimethyl­amide)
title_full O,O′-Di-p-tolyl­pyrophospho­ric bis­(dimethyl­amide)
title_fullStr O,O′-Di-p-tolyl­pyrophospho­ric bis­(dimethyl­amide)
title_full_unstemmed O,O′-Di-p-tolyl­pyrophospho­ric bis­(dimethyl­amide)
title_short O,O′-Di-p-tolyl­pyrophospho­ric bis­(dimethyl­amide)
title_sort o,o′-di-p-tolyl­pyrophospho­ric bis­(dimethyl­amide)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979840/
https://www.ncbi.nlm.nih.gov/pubmed/21579865
http://dx.doi.org/10.1107/S1600536810002692
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AT ghadimisaied oodiptolylpyrophosphoricbisdimethylamide
AT ebrahimivalmoozialiasghar oodiptolylpyrophosphoricbisdimethylamide

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